Benchmark values for the Soret, thermal diffusion and diffusion coefficients of three binary organic liquid mixtures

• Published in: Philosophical magazine (Abingdon, England) Vol. 83; no. 17-18; pp. 1965 - 1971
• Main Authors: Platten, J. K., Bou-Ali, M. M., Costesèque, P., Dutrieux, J. F., Köhler, W., Leppla, C., Wiegand, S., Wittko, G.
• Format: Journal Article
• Language: English
• Published: Taylor & Francis Group 01.01.2003
• ISSN: 1478-6435; 1478-6443
• DOI: 10.1080/0141861031000108204

With the aim of providing reliable benchmark values, we have measured the Soret, diffusion and thermal diffusion coefficients of the three binary mixtures of dodecane, isobutylbenzene and 1,2,3,4 tetrahydronaphthalene for a concentration of 50 wt% at a temperature of 25C. The experimental techniques applied by the five participating laboratories are transient holographic gratings, annular and parallelepipedic thermogravitational columns, and vertical parallelepipedic columns with velocity amplitude determination by laser doppler velocimetry. The systems have also been studied in a annular thermogravitational column filled with a porous medium in the gap. There is a good agreement between the different experiments with deviations of the order of a few per cent in most cases (8.5% at most). The numerical values are tabulated in the paper.