Direct Evidence of Ice Crystallization Inhibition by Dielectric Relaxation of Hydrated Ions

• Published in: Materials Vol. 14; no. 22; p. 6975
• Main Authors: Song, Xiaoyuan, Zhong, Lisheng, Gao, Jinghui
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 18.11.2021; MDPI
• Subjects: Alternating current; Aqueous solutions; Cooling; Cryopreservation; Crystal growth; Crystallization; Dielectric relaxation; Differential scanning calorimetry; electric field; Electric fields; Electrodes; Frequency ranges; Heat; hydrated ions; Ice crystals; Microelectrodes; Phase transitions; Physical properties; Tissues
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma14226975

In this paper, the inhibition effect of an alternative current (AC) electric field on ice crystallization in 0.9 wt % NaCl aqueous solution was confirmed thermodynamically with characterization. An innovative experimental and analytical method, combining differential scanning calorimeter (DSC) measurement with an externally applied electric field was created by implanting microelectrodes in a sample crucible. It was found that the ice crystallization, including pure ice and salty ice, was obviously inhibited after field cooling with an external AC electric field in a frequency range of 100 k–10 MHz, and the crystallization ratio was related to frequency. Compared with non-field cooling, the crystallization ratio of ice crystals was reduced to less than 20% when E = 57.8 kV/m and f = 1 MHz. The dielectric spectrum results show that this inhibition effect of an alternating electric field on ice crystal growth is closely related to the dielectric relaxation process of hydrated ions.