Trimethylsilyl triflate mediated new carbon-carbon bond forming reactions between benzyl diphenylphosphinates and organosilicon compounds

The trimethylsilyl triflate mediated reaction of benzyl diphenylphosphinate with allyltrimethylsilane or trimethylsilyl enolate afforded the corresponding cross-coupling products in good yields.

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Bibliographic Details
Published inChemistry letters Vol. 34; no. 6; pp. 756 - 757
Main Authors Kobashi, Y, Minowa, T, Mukaiyama, T
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 05.06.2005
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
COUPLING REACTIONS
ETHERS
ALLYLSILANES
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Summary:The trimethylsilyl triflate mediated reaction of benzyl diphenylphosphinate with allyltrimethylsilane or trimethylsilyl enolate afforded the corresponding cross-coupling products in good yields.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2005.756