Research and Development of Novel Refractory of MgO Doped with ZrO2 Nanoparticles for Copper Slag Resistance

• Published in: Materials Vol. 14; no. 9; p. 2277
• Main Authors: Gómez-Rodríguez, Cristian, Antonio-Zárate, Yanet, Revuelta-Acosta, Josept, Verdeja, Luis Felipe, Fernández-González, Daniel, López-Perales, Jesús Fernando, Rodríguez-Castellanos, Edén Amaral, García-Quiñonez, Linda Viviana, Castillo-Rodríguez, Guadalupe Alan
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 28.04.2021; MDPI
• Subjects: Alumina; ceramic composites; Ceramic powders; Chemical attack; Communication; Copper; Copper industry; corrosion; Corrosion mechanisms; Corrosion resistance; Corrosion tests; Densification; Furnaces; Grain boundaries; Grain growth; Magnesium oxide; Metallurgy; MgO refractories; Nanoparticles; Particle size; Physical properties; R&D; Research & development; Sintering (powder metallurgy); Slag; zirconia; Zirconium dioxide; Mexico
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma14092277

This study investigates the corrosion mechanism on 100 wt.% MgO and 95 wt.% MgO with 5 wt.% nano-ZrO2 ceramic composites. First, MgO powder and powder mixtures (MgO + nano ZrO2) were uniaxially and isostatically pressed; then, they were sintered at 1650 °C. Corrosion by copper slag was studied in sintered samples. Physical properties, microstructure, and penetration of the slag in the refractory were studied. Results reveal that ZrO2 nanoparticles enhanced the samples’ densification, promoting grain growth due to diffusion of vacancies during the sintering process. Additionally, magnesia bricks were severely corroded, if compared with those doped with nano-ZrO2, mainly due to the dissolution of MgO grains during the chemical attack by copper slag.