Neopentyl Glycol as Active Supporting Media in Shape-Stabilized PCMs

• Published in: Materials Vol. 12; no. 19; p. 3169
• Main Authors: Serrano, Angel, Dauvergne, Jean-Luc, Doppiu, Stefania, Palomo Del Barrio, Elena
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 27.09.2019; MDPI
• Subjects: Alkanes; Chemical compatibility; docosane; Energy storage; expanded graphite; Flux density; Graphite; Heat; Heat storage; Latent heat; neopentyl glycol; Phase change materials; Phase transitions; Porous materials; shape-stabilized phase change material; Solid phases; solid-solid pcm; Stability; Storage capacity; Temperature; Thermal energy; thermal energy storage; Wettability
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma12193169

The present work explores the feasibility of using polyalcohols with solid-solid phase transition as active supporting matrix of n-alkanes in shape-stabilized phase change materials (SSPCMs). It is well-established that the use of SSPCM avoids leakage and increases stability and easy handling of solid-liquid PCMs. Nevertheless, the resulting composite exhibits a loss of heat storage capacity due to the volume occupied by the supporting material, which does not contribute to latent heat storage. Therefore, the objective of this work is to combine solid-liquid PCMs (alkanes) with solid-solid PCMs (polyalcohols), both exhibiting a phase transition in the same range of temperature, to obtain high energy density SSPCMs. Towards that goal, the performance of Neopentyl Glycol (NPG) and Docosane as a new energetic SSPCM has been proved. The NPG-Docosane chemical compatibility and its outstanding wettability facilitate the propitious association of both materials. The higher capillary forces obtained by decreasing the NPG crystal size together with the addition of expanded graphite (EG) allowed to obtain a maximum Docosane content of 60 wt%. The addition of EG improves the shape stability at the time that increases the heat transfer properties of the composites. The analysis showed that the components of the obtained SSPCMs are able to combine their latent heats, achieving a maximum value of 210.74 J/g for the highest Docosane content. This value is much higher than those latent heats exhibited by existing SSPCMs in the same working temperature range.