The use of a rigid tritopic phosphonic ligand for the synthesis of a robust honeycomb-like layered zirconium phosphonate framework

1,3,5-Tris(4-phosphonophenyl)benzene was synthesized via a microwave heating assisted route and was subsequently used for the preparation of a new zirconium phosphonate with honeycomb-like structure displaying remarkable thermal stability and hydrolysis resistance.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 43; pp. 5737 - 5740
Main Authors Taddei, Marco, Costantino, Ferdinando, Vivani, Riccardo, Sabatini, Stefano, Lim, Sang-Ho, Cohen, Seth M
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 01.01.2014
Subjects
Heating
Hydrolysis
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Ligands
Microwaves
Phosphonates
Robustness
Synthesis
Zirconium
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Summary:1,3,5-Tris(4-phosphonophenyl)benzene was synthesized via a microwave heating assisted route and was subsequently used for the preparation of a new zirconium phosphonate with honeycomb-like structure displaying remarkable thermal stability and hydrolysis resistance.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
FG02-08ER46519
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc01253d