All-Inorganic Colloidal Quantum Dot Photovoltaics Employing Solution-Phase Halide Passivation

A new solution‐phase halide passivation strategy to improve the electronic properties of colloidal quantum dot films is reported. We prove experimentally that the approach leads to an order‐of‐magnitude increase in mobility and a notable reduction in trap state density. We build solar cells having t...

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Published inAdvanced materials (Weinheim) Vol. 24; no. 47; pp. 6295 - 6299
Main Authors Ning, Zhijun, Ren, Yuan, Hoogland, Sjoerd, Voznyy, Oleksandr, Levina, Larissa, Stadler, Philipp, Lan, Xinzheng, Zhitomirsky, David, Sargent, Edward H.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 11.12.2012
WILEY‐VCH Verlag
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Summary:A new solution‐phase halide passivation strategy to improve the electronic properties of colloidal quantum dot films is reported. We prove experimentally that the approach leads to an order‐of‐magnitude increase in mobility and a notable reduction in trap state density. We build solar cells having the highest efficiency (6.6%) reported using all‐inorganic colloidal quantum dots. The improved photocurrent results from increased efficiency of collection of infrared‐generated photocarriers.
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ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201202942