Investigation of biomass alkali release in a dual circulating fluidized bed chemical looping combustion system

• Published in: Fuel (Guildford) Vol. 297; p. 120743
• Main Authors: Gogolev, Ivan, Pikkarainen, Toni, Kauppinen, Juho, Linderholm, Carl, Steenari, Britt-Marie, Lyngfelt, Anders
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.08.2021; Elsevier BV
• Subjects: Absorption; Alkali; Alkalies; Alkalis; Alkalizing; Aluminosilicates; Aluminum silicates; Ash; Biomass; Biomass burning; Carbon sequestration; Chemical looping combustion; Combustion; Emissions; Flue gas; Fluidized bed combustion; Fluidized beds; Fuels; Hardwoods; Heat exchangers; Ilmenite; Ionization; Ionization counters; Manganates; Nuclear fuels; Oxygen; Oxygen carriers; Pellets; Reactors; Retention; Silicates; Steam; Surface ionization; Titanates; Oxygen carriers; Alkali; Biomass; Chemical looping combustion
• ISSN: 0016-2361; 1873-7153
• DOI: 10.1016/j.fuel.2021.120743

•Gas-phase alkali release is higher in CLC vs OCAC operation.•FR steam atmosphere enhances gas-phase alkali release in CLC.•Alkali retention >97% for ilmenite, >92% for braunite oxygen carrier.•AR emissions occur due to carryover of unconverted fuel from the FR to the AR. Chemical looping combustion (CLC) of biomass is a promising technology for power generation with integrated carbon capture. In CLC, alkali content of biomass poses potential issues of bed agglomeration, as well as heat exchanger fouling and corrosion. The fate of biomass alkalis was investigated in a dual-interconnected circulating fluidized bed CLC system. Experiments were conducted in oxygen carrier aided combustion (OCAC) and CLC modes. Ilmenite and braunite oxygen carriers and three biomass fuels (wood pellets, wood char, straw pellets) were tested. Flue gas alkali emissions in the air reactor (AR) and fuel reactor (FR) were measured with a surface ionization detector (SID). Results showed that CLC operation yields gas-phase alkali emissions that are up to 15 times higher than in comparable OCAC operation. Results analysis concluded that increased alkali emissions in CLC arise from the steam atmosphere in the FR, whereby steam accelerates the decomposition of alkali compounds in the biomass. Retention of alkalis in the condensed phase was found to be >97% for ilmenite and >92% for braunite CLC operation. Up to 60–80% of the retention was attributed to fuel ash formation. The residual retention was attributed to absorption of alkalis by the oxygen carriers. Absorption likely occurred mainly through formation of alkali manganates and silicates in braunite, and formation of alkali silicates, aluminosilicates, manganates, and titanates in ilmenite. Gas-phase alkali emissions in the AR, although less than in the FR, were found to occur due to combustion of unconverted fuel carried over from the FR to the AR.