Sandstone injectivity and salt stability of cellulose nanocrystals (CNC) dispersions—Premises for use of CNC in enhanced oil recovery

• Published in: Industrial crops and products Vol. 93; pp. 152 - 160
• Main Authors: Molnes, Silje N., Torrijos, Ivan P., Strand, Skule, Paso, Kristofer G., Syverud, Kristin
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 25.12.2016
• Subjects: CNC; Injectivity; Nanocellulose; Oil recovery; Salt stability; CNC; Salt stability; Nanocellulose; Oil recovery; Injectivity
• ISSN: 0926-6690; 1872-633X; 1872-633X
• DOI: 10.1016/j.indcrop.2016.03.019

•Cellulose nanocrystal (CNC) injectivity into porous sandstone has been investigated.•The colloidal stability of CNC in low salinity brine (1000ppm NaCl in de-ionized water) has been evaluated.•It is possible to inject CNC into sandstone, using low salinity brine.•CNC has a good colloidal stability when dispersed in a low salinity solution.•These observations are important premises for further investigation of the use of CNC as a flooding additive for enhanced oil recovery (EOR). Reservoir production is frequently supported by using flooding fluids, often seawater. The efficiency is affected by various factors, such as the wettability of the reservoir rock and the mobility ratio between reservoir oil and injected fluid phase. These factors again influence sweep efficiency, which is the fraction of the total reservoir oil volume in contact with injected fluid during oil recovery. Addition of nanoparticles can affect the sweep efficiency on a macroscopic level by increasing the volume of petroleum in contact with the flooding fluid. Presented here are core-flooding studies performed using cellulose nanocrystals (CNC) of different concentrations in low-saline water. The studies were performed to investigate the injectivity of CNC into a high-permeable sandstone core, and to observe the effects addition of electrolytes had on the rheological properties of a low concentration dispersion of CNC. Zeta- potential and shear viscosity of dilute dispersions containing CNC was investigated under increasing electrolyte concentration. The flooding experiments show that the CNC has good injectivity in sandstone for all concentrations used, and the viscosity measurements performed on the effluent prove that the particles are able to travel through the core. Being sufficiently small for injection into sandstone and showing good colloidal stability at low salinities, CNC particles have the premises necessary to function properly as a flooding additive for enhanced oil recovery (EOR) in sandstone reservoirs.