Formation of the world's largest REE deposit through protracted fluxing of carbonatite by subduction-derived fluids

• Published in: Scientific reports Vol. 3; no. 1; p. 1776
• Main Authors: Ling, Ming-Xing, Liu, Yu-Long, Williams, Ian S., Teng, Fang-Zhen, Yang, Xiao-Yong, Ding, Xing, Wei, Gang-Jian, Xie, Lu-Hua, Deng, Wen-Feng, Sun, Wei-Dong
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 07.05.2013; Nature Publishing Group
• Subjects: 704/2151/209; 704/2151/213; 704/2151/330; 704/2151/431; Calcite; Crystals; Dolomite; Humanities and Social Sciences; Isotopes; Mineralization; multidisciplinary; Rare earth elements; Science
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/srep01776

Rare Earth Elements (REE) are essential to modern society but the origins of many large REE deposits remain unclear. The U-Th-Pb ages, chemical compositions and C, O and Mg isotopic compositions of Bayan Obo, the world's largest REE deposit, indicate a protracted mineralisation history with unusual chemical and isotopic features. Coexisting calcite and dolomite are in O isotope disequilibrium; some calcitic carbonatite samples show highly varied δ 26 Mg which increases with increasing Si and Mg; and ankerite crystals show decreases in Fe and REE from rim to centre, with highly varied REE patterns. These and many other observations are consistent with an unusual mineralisation process not previously considered; protracted fluxing of calcitic carbonatite by subduction-released high-Si fluids during the closure of the Palaeo-Asian Ocean. The fluids leached Fe and Mg from the mantle wedge and scavenged REE, Nb and Th from carbonatite, forming the deposit through metasomatism of overlying sedimentary carbonate.