Influence of ionic liquid content on properties of dense polymer membranes

Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF 4]) io...

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Published inEuropean polymer journal Vol. 45; no. 3; pp. 813 - 819
Main Authors Kohoutová, M., Sikora, A., Hovorka, Š., Randová, A., Schauer, J., Tišma, M., Setničková, K., Petričkovič, R., Guernik, S., Greenspoon, N., Izák, P.
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Published Kidlington Elsevier Ltd 01.03.2009
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Abstract Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF 4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF 4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF 4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF 4] in PDMS-[BBIM][BF 4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths.
AbstractList Pervaporation was used for removal of butan-1-ol from its 5wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF sub(4)]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF sub(4)] membranes (though optically homogeneous) contained PDMS and [BBIM][BF sub(4)] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF sub(4)] in PDMS-[BBIM][BF sub(4)] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths.
Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF 4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF 4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF 4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF 4] in PDMS-[BBIM][BF 4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths.
Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF4] in PDMS-[BBIM][BF4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths.
Author Guernik, S.
Kohoutová, M.
Izák, P.
Tišma, M.
Schauer, J.
Hovorka, Š.
Sikora, A.
Setničková, K.
Petričkovič, R.
Greenspoon, N.
Randová, A.
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  email: izak@icpf.cas.cz
  organization: Department of Separation Processes, Institute of Chemical Process Fundamentals, Rozvojová 135, 165 02 Prague 6, Czech Republic
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Issue 3
Keywords Ionic liquids
Dense polymer membranes
Biofuel
Fermentation
Pervaporation
Water
Dimethylsiloxane polymer
Imidazole derivatives
Transport properties
Separation capacity
Iminium compounds
Experimental study
Ionic liquid
Concentration effect
Butanol
Membrane
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    fullname: Wasserscheid
– volume: 102
  start-page: 3667
  year: 2002
  ident: 10.1016/j.eurpolymj.2008.11.043_bib9
  publication-title: Chem. Rev.
  doi: 10.1021/cr010338r
  contributor:
    fullname: Duppont
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Snippet Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to...
Pervaporation was used for removal of butan-1-ol from its 5wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to...
Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to...
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SubjectTerms Applied sciences
Biofuel
Clostridium acetobutylicum
Dense polymer membranes
Exact sciences and technology
Exchange resins and membranes
Fermentation
Forms of application and semi-finished materials
Ionic liquids
Pervaporation
Polymer industry, paints, wood
Technology of polymers
Title Influence of ionic liquid content on properties of dense polymer membranes
URI https://dx.doi.org/10.1016/j.eurpolymj.2008.11.043
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