Influence of ionic liquid content on properties of dense polymer membranes
Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF 4]) io...
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Published in | European polymer journal Vol. 45; no. 3; pp. 813 - 819 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
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01.03.2009
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Abstract | Pervaporation was used for removal of butan-1-ol from its 5
wt.% of aqueous solution, at which the concentration of
Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30
wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF
4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF
4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF
4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF
4] in PDMS-[BBIM][BF
4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths. |
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AbstractList | Pervaporation was used for removal of butan-1-ol from its 5wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF sub(4)]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF sub(4)] membranes (though optically homogeneous) contained PDMS and [BBIM][BF sub(4)] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF sub(4)] in PDMS-[BBIM][BF sub(4)] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths. Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF 4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF 4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF 4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF 4] in PDMS-[BBIM][BF 4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths. Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF4] in PDMS-[BBIM][BF4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths. |
Author | Guernik, S. Kohoutová, M. Izák, P. Tišma, M. Schauer, J. Hovorka, Š. Sikora, A. Setničková, K. Petričkovič, R. Greenspoon, N. Randová, A. |
Author_xml | – sequence: 1 givenname: M. surname: Kohoutová fullname: Kohoutová, M. organization: Department of Separation Processes, Institute of Chemical Process Fundamentals, Rozvojová 135, 165 02 Prague 6, Czech Republic – sequence: 2 givenname: A. surname: Sikora fullname: Sikora, A. organization: Institute of Macromolecular Chemistry, Heyrovského nám. 2, 162 06 Prague 6, Czech Republic – sequence: 3 givenname: Š. surname: Hovorka fullname: Hovorka, Š. organization: Institute of Chemical Technology, Technická 5, 160 00 Prague 6, Czech Republic – sequence: 4 givenname: A. surname: Randová fullname: Randová, A. organization: Institute of Chemical Technology, Technická 5, 160 00 Prague 6, Czech Republic – sequence: 5 givenname: J. surname: Schauer fullname: Schauer, J. organization: Institute of Macromolecular Chemistry, Heyrovského nám. 2, 162 06 Prague 6, Czech Republic – sequence: 6 givenname: M. surname: Tišma fullname: Tišma, M. organization: Faculty of Food Technology, University of J.J. Strossmayer in Osijek, F. Kuhača 18, 31 000 Osijek, Croatia – sequence: 7 givenname: K. surname: Setničková fullname: Setničková, K. organization: Department of Separation Processes, Institute of Chemical Process Fundamentals, Rozvojová 135, 165 02 Prague 6, Czech Republic – sequence: 8 givenname: R. surname: Petričkovič fullname: Petričkovič, R. organization: Department of Separation Processes, Institute of Chemical Process Fundamentals, Rozvojová 135, 165 02 Prague 6, Czech Republic – sequence: 9 givenname: S. surname: Guernik fullname: Guernik, S. organization: Chemada Fine Chemicals, Nir Itzhak D.N. HaNegev 85455, Israel – sequence: 10 givenname: N. surname: Greenspoon fullname: Greenspoon, N. organization: Chemada Fine Chemicals, Nir Itzhak D.N. HaNegev 85455, Israel – sequence: 11 givenname: P. surname: Izák fullname: Izák, P. email: izak@icpf.cas.cz organization: Department of Separation Processes, Institute of Chemical Process Fundamentals, Rozvojová 135, 165 02 Prague 6, Czech Republic |
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Keywords | Ionic liquids Dense polymer membranes Biofuel Fermentation Pervaporation Water Dimethylsiloxane polymer Imidazole derivatives Transport properties Separation capacity Iminium compounds Experimental study Ionic liquid Concentration effect Butanol Membrane |
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Snippet | Pervaporation was used for removal of butan-1-ol from its 5
wt.% of aqueous solution, at which the concentration of
Clostridium acetobutylicum starts to... Pervaporation was used for removal of butan-1-ol from its 5wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to... Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to... |
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SubjectTerms | Applied sciences Biofuel Clostridium acetobutylicum Dense polymer membranes Exact sciences and technology Exchange resins and membranes Fermentation Forms of application and semi-finished materials Ionic liquids Pervaporation Polymer industry, paints, wood Technology of polymers |
Title | Influence of ionic liquid content on properties of dense polymer membranes |
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