Synthesis of Highly Stable, Water-Dispersible Copper Nanoparticles as Catalysts for Nitrobenzene Reduction

• Published in: Chemistry, an Asian journal Vol. 9; no. 1; pp. 189 - 198
• Main Authors: Kaur, Ravneet, Giordano, Cristina, Gradzielski, Michael, Mehta, Surinder K.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.01.2014; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: Acrylic Resins - chemistry; Aminophenols - chemical synthesis; Aminophenols - chemistry; Catalysis; Chemistry; copper; Copper - chemistry; Metal Nanoparticles - chemistry; Molecular Structure; nanoparticles; Nitrophenols - chemistry; Oxidation-Reduction; Particle Size; reduction; Surface Properties; surfactants; Water - chemistry; catalysis; copper; surfactants; nanoparticles; reduction
• ISSN: 1861-4728; 1861-471X
• DOI: 10.1002/asia.201300809

We report an aqueous‐phase synthetic route to copper nanoparticles (CuNPs) using a copper–surfactant complex and tests of their catalytic efficiency for a simple nitrophenol reduction reaction under atmospheric conditions. Highly stable, water‐dispersed CuNPs were obtained with the aid of polyacrylic acid (PAA), but not with other dispersants like surfactants or polymethacrylic acid (PMAA). The diameter of the CuNPs could be controlled in the range of approximately 30–85 nm by modifying the ratio of the metal precursor to PAA. The catalytic reduction of p‐nitrophenol to p‐aminophenol takes place at the surface of CuNPs at room temperature and was accurately monitored by UV/Vis spectroscopy. The catalytic efficiency was found to be remarkably high for these PAA‐capped CuNPs, given the fact that at the same time PAA is efficiently preventing their oxidation as well. The activity was found to increase as the size of the CuNPs decreased. It can therefore be concluded that the synthesized CuNPs are catalytically highly efficient in spite of the presence of a protective PAA coating, which provides them with a long shelf life and thereby enhances the application potential of these CuNPs. Stable relationship: Highly stable, water‐dispersible CuNPs were synthesized using a metal–surfactant complex and polyacrylic acid. The NPs displayed outstanding catalytic activity in the reduction of 4‐nitrophenol to aminophenol (see figure).