A Convenient Palladium-Catalyzed Carbonylative Synthesis of Benzofuran-2(3 H)-ones with Formic Acid as the CO Source

A general and convenient palladium‐catalyzed carbonylation procedure for the synthesis of benzofuran‐2(3 H)‐ones from phenols and aldehydes has been developed. With formic acid as the CO source, a variety of benzofuran‐2(3 H)‐ones were obtained in moderate to good yields. Competent reaction: A gener...

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Published inChemistry, an Asian journal Vol. 11; no. 17; pp. 2453 - 2457
Main Authors Qi, Xinxin, Li, Hao-Peng, Wu, Xiao-Feng
Format Journal Article
LanguageEnglish
Published Germany Blackwell Publishing Ltd 06.09.2016
Wiley Subscription Services, Inc
Subjects
carbonylation
cascade reaction
Chemistry
CO-free
heterocycle synthesis
palladium
palladium
heterocycle synthesis
cascade reaction
carbonylation
CO-free
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Summary:A general and convenient palladium‐catalyzed carbonylation procedure for the synthesis of benzofuran‐2(3 H)‐ones from phenols and aldehydes has been developed. With formic acid as the CO source, a variety of benzofuran‐2(3 H)‐ones were obtained in moderate to good yields. Competent reaction: A general and efficient palladium‐catalyzed carbonylation procedure for the synthesis of benzofuran‐2(3 H)‐ones from phenols and aldehydes has been developed. With formic acid as the CO source, a variety of benzofuran‐2(3 H)‐ones were obtained in moderate to good yields.
Bibliography:istex:94986E8518299E1DB0527204CD54B2EA51811CF4
NSFC - No. 21472174
ArticleID:ASIA201600873
ark:/67375/WNG-DB69MZSV-W
Zhejiang Natural Science Fund for Distinguished Young Scholars - No. LR16B020002
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201600873