Kinetic and structural studies on 'tethered' Ru(II) arene ketone reduction catalysts

A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using (1)H NMR spectroscopy.

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Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 39; no. 5; pp. 1395 - 1402
Main Authors Cheung, Fung Kei Kathy, Clarke, Adam J, Clarkson, Guy J, Fox, David J, Graham, Mark A, Lin, Changxue, Crivillé, Adriana Lorente, Wills, Martin
Format Journal Article
LanguageEnglish
Published England 01.01.2010
Subjects
Asymmetry
Catalysis
Catalysts
Crystallography, X-Ray
Hydrogenation
Ketones
Ketones - chemistry
Kinetics
Molecular Conformation
Monitoring
NMR spectroscopy
Oxidation-Reduction
Reaction kinetics
Ruthenium
Ruthenium - chemistry
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Summary:A series of kinetic and structural investigations on ruthenium-based catalysts for asymmetric transfer hydrogenation (ATH) of ketones are reported. A method is reported for monitoring the formation of ruthenium hydride species in real time using (1)H NMR spectroscopy.
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ISSN:1477-9226
1477-9234
DOI:10.1039/b915932k