Recent progress in g-C3N4, TiO2 and ZnO based photocatalysts for dye degradation: Strategies to improve photocatalytic activity

• Published in: The Science of the total environment Vol. 767; p. 144896
• Main Authors: Nemiwal, Meena, Zhang, Tian C., Kumar, Dinesh
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.05.2021
• Subjects: absorption; adsorption; coagulation; crystal structure; Dyes; environment; g-C3N4, TiO2 and ZnO; Heterostructured nanocomposite; human health; light; nanocomposites; photocatalysis; photocatalysts; Photocatalytic degradation; photolysis; semiconductors; solar energy; synergism; titanium dioxide; water pollution; Photocatalytic degradation; Dyes; Heterostructured nanocomposite; g-C3N4, TiO2 and ZnO
• ISSN: 0048-9697; 1879-1026; 1879-1026
• DOI: 10.1016/j.scitotenv.2020.144896

Water contamination by dyes is a matter of concern for human health and the environment. Various methods (membrane separation, coagulation and adsorption) have been explored to remove/degrade dyes. However, now the exploitation of semiconductor assisted materials using renewable solar energy has emerged as a potential candidate to resolve the issue. Although, single component photocatalysts (ZnO, TiO2, ZrO2) were experimented, due to their low efficiency and stability due to the high recombination rate electron-hole pair and inefficient visible light absorption, composites of semiconductor materials are being used. Semiconductor heterojunction systems are developed by coupling two or more semiconductor components. The synergistic effect of their properties, such as adsorption and improved charge carrier migration, is observed to increase overall stability. This review covers recent progress in advanced nanocomposite materials based on g-C3N4, TiO2 and ZnO used as photocatalysts with details of enhancing the photocatalytic properties by heterojunctions, crystallinity and doping. The conclusion at the end displays a summary, research gaps and future outlook. A holistic analysis of recent progress to demonstrate the efficient heterojunctions for photodegradation with optimal conditions, this review will be helpful for the development of efficient heterostructured systems for photodegradation. This review covers references from the year 2017–2020. [Display omitted] •Mechanistic development in the charge carrier's movement for dye degradation•Graphitic carbon nitride (g-C3N4) TiO2, ZnO based photocatalysts•Improved photocatalysis using heterojunctions, crystal phase and facet, doping