Electrochemical Switching of the Cubic Nonlinear Optical Properties of an Aryldiethynyl-Linked Heterobimetallic Complex between Three Distinct States
Successive oxidation processes in a heterobimetallic iron–ruthenium complex (see picture) “switch” the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.
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Published in | Angewandte Chemie (International ed.) Vol. 45; no. 44; pp. 7376 - 7379 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
13.11.2006
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Summary: | Successive oxidation processes in a heterobimetallic iron–ruthenium complex (see picture) “switch” the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex. |
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Bibliography: | istex:B26C6E801E5415A9AEFFDD0A1937F6EA78F5BE9B ArticleID:ANIE200602684 CNRS We thank the Australian Research Council (ARC) and the CNRS for financial support. This project is supported by the International Science Linkages Programme established under the Australian Government's innovation statement, Backing Australia's Ability. F.P. and N.G. thank Region Bretagne for financial support. M.G.H. thanks Johnson Matthey Technology Centre for the generous loan of ruthenium salts. M.G.H. is an ARC Australian Professorial Fellow and M.P.C. is an ARC Australian Research Fellow. ark:/67375/WNG-SSFZH3TG-Z Australian Research Council ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200602684 |