A Purely Organic Molecular Metal Based on a Hydrogen-Bonded Charge-Transfer Complex: Crystal Structure and Electronic Properties of TTF-Imidazole-p-Chloranil

Modification of tetrathiafulvalene with an imidazolyl substituent as a hydrogen‐bond donor allows the generation of a hydrogen‐bonded 2:1 charge‐transfer complex with chloranil. This complex forms a three‐dimensional network with columnar stacking of each component and multiple S⋅⋅⋅S interactions (s...

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Published inAngewandte Chemie International Edition Vol. 43; no. 46; pp. 6343 - 6346
Main Authors Murata, Tsuyoshi, Morita, Yasushi, Fukui, Kozo, Sato, Kazunobu, Shiomi, Daisuke, Takui, Takeji, Maesato, Mitsuhiko, Yamochi, Hideki, Saito, Gunzi, Nakasuji, Kazuhiro
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 26.11.2004
WILEY‐VCH Verlag
Subjects
conducting materials
crystal engineering
hydrogen bonds
magnetic properties
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Summary:Modification of tetrathiafulvalene with an imidazolyl substituent as a hydrogen‐bond donor allows the generation of a hydrogen‐bonded 2:1 charge‐transfer complex with chloranil. This complex forms a three‐dimensional network with columnar stacking of each component and multiple S⋅⋅⋅S interactions (see picture). This strongly hydrogen‐bonded purely organic conducting material is the first to display metallic behavior.
Bibliography:ark:/67375/WNG-92SZPMX2-B
ArticleID:ANIE200460801
This work was partially supported by PRESTO-JST, and by 21COE program "Creation of Integrated EcoChemistry of Osaka University".
istex:2A703F4F5C35106EA0902D1BA5DAF070DA9E618B
This work was partially supported by PRESTO‐JST, and by 21COE program “Creation of Integrated EcoChemistry of Osaka University”.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460801