Gold(III)-Catalyzed Propargylic Substitution Reaction Followed by Cycloisomerization for Synthesis of Poly-Substituted Furans from N -Tosylpropargyl Amines with 1,3-Dicarbonyl Compounds
The treatment of -tosylpropargyl amines with 1,3-dicarbonyl compounds in the presence of AuBr (5 mol%) and AgOTf (15 mol%) afforded poly-substituted furans in good-to-high yields via the gold-catalyzed cleavage of the sp carbon-nitrogen bond.
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Published in | Molecules (Basel, Switzerland) Vol. 29; no. 2; p. 378 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Switzerland
MDPI AG
11.01.2024
MDPI |
Subjects | |
Online Access | Get full text |
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Summary: | The treatment of
-tosylpropargyl amines
with 1,3-dicarbonyl compounds
in the presence of AuBr
(5 mol%) and AgOTf (15 mol%) afforded poly-substituted furans
in good-to-high yields via the gold-catalyzed cleavage of the sp
carbon-nitrogen bond. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1420-3049 1420-3049 |
DOI: | 10.3390/molecules29020378 |