Photocatalytic degradation of tetracycline hydrochloride with g-C3N4/Ag/AgBr composites

• Published in: Frontiers in chemistry Vol. 10; p. 1069816
• Main Authors: Song, Jiahe, Zhao, Kun, Yin, Xiangbin, Liu, Ying, Khan, Iltaf, Liu, Shu-Yuan
• Format: Journal Article
• Language: English
• Published: Frontiers Media S.A 14.11.2022
• Subjects: Ag/AgBr; Chemistry; G-C3N4; photocatalytic degradation; tetracycline hydrochloride; Z-scheme heterojunction
• ISSN: 2296-2646; 2296-2646
• DOI: 10.3389/fchem.2022.1069816

Graphite carbon nitride (g-C 3 N 4 ), as a polymer semiconductor photocatalyst, is widely used in the treatment of photocatalytic environmental pollution. In this work, a Z-scheme g-C 3 N 4 /Ag/AgBr heterojunction photocatalyst was prepared based on the preparation of a g-C 3 N 4 -based heterojunction via in-situ loading through photoreduction method. The g-C 3 N 4 /Ag/AgBr composite showed an excellent photocatalytic performance in the degradation of tetracycline hydrochloride pollutants. Among the prepared samples, g-C 3 N 4 /Ag/AgBr-8% showed the best photocatalytic ability for the degradation of tetracycline hydrochloride, whose photocatalytic degradation kinetic constant was 0.02764 min −1 , which was 9.8 times that of g-C 3 N 4 , 2.4 times that of AgBr, and 1.9 times that of Ag/AgBr. In the photocatalytic process, • O 2– and • OH are main active oxygen species involved in the degradation of organic pollutants. The photocatalytic mechanism of g-C 3 N 4 /Ag/AgBr is mainly through the formation of Z-scheme heterojunctions, which not only effectively improves the separation efficiency of photogenerated electron-hole pairs, but also maintains the oxidation and reduction capability of AgBr and g-C 3 N 4 , respectively.