Polarity-dependence of the nonlinear dielectric response in interfacial water

• Published in: The Journal of chemical physics Vol. 158; no. 13; pp. 134716 - 134724
• Main Authors: Mulpuri, N., Bratko, D.
• Format: Journal Article
• Language: English
• Published: United States American Institute of Physics 07.04.2023; American Institute of Physics (AIP)
• Subjects: Chemistry; Coupling (molecular); Electric fields; Field strength; Graphene; Molecular dynamics; Nonlinear response; Permittivity; Physics; Solid phases; Tensors; Water chemistry
• ISSN: 0021-9606; 1089-7690; 1089-7690
• DOI: 10.1063/5.0142483

Molecular dynamics simulations are used to study the nonlinear dielectric responses of a confined aqueous film in a planar nanopore under perpendicular electric fields at varied voltages between confining graphene sheets. Dielectric saturation reminiscent of the bulk phase behavior is prevalent at very strong fields, whereas we observe a nonmonotonic permittivity dependence on the electric field at intermediate strengths where field-alignment and spontaneous polarization of interfacial water are of comparable magnitude. The coupling between the two effects results in distinct dielectric responses at opposite confinement walls. The normal component of both the differential dielectric constant and dielectric difference constant tensors averaged over the region closer to the wall under an incoming electric field (field pointing from the liquid to the solid phase) initially increases with the strength of the imposed field. The differential permittivity peaks at a field strength previously shown to offset the surface-induced orientation bias of hydration molecules at this wall. Further strengthening of the field results in a conventional saturation behavior. At the opposite wall (subject to outgoing field) and in the central region of the water slab, the nonlinear dielectric response resembles bulklike saturation. The conditions at the permittivity extremum coincide with the window of accelerated reorientation rates of interfacial water molecules under an incoming field we uncovered in earlier molecular dynamics analyses.