Oxidation stability of yeast biodiesel using Rancimat analysis: validation using infrared spectroscopy and gas chromatography–mass spectrometry

Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there are only few articles dealing with the stability of the microbial biofuels. Hence, this study aimed at characterizing the storage time of bio...

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Published inEnvironmental science and pollution research international Vol. 26; no. 3; pp. 3075 - 3090
Main Authors Tamilalagan, Anbarasan, Singaram, Jayanthi
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg Springer Berlin Heidelberg 01.01.2019
Springer Nature B.V
Subjects
Alternative fuels
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Biodegradation
biodiesel
Biodiesel fuels
Biofuels
Chromatography
Degradation
Degradation products
Diesel
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental science
Gas chromatography
gas chromatography-mass spectrometry
Industrial wastes
Infrared analysis
Infrared spectroscopy
Mass spectrometry
Mass spectroscopy
microbial oils
Microorganisms
Oxidation
oxidative stability
Research Article
Shelf life
spectral analysis
Stability analysis
Storage conditions
storage quality
Storage stability
storage time
Waste Water Technology
Water Management
Water Pollution Control
Yeast
yeasts
Induction time
Microbial biodiesel
Thermal oxidative stability
Fourier-transform infrared spectroscopy
Storage stability
Gas chromatography–mass spectrometry
Online AccessGet full text

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Abstract Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there are only few articles dealing with the stability of the microbial biofuels. Hence, this study aimed at characterizing the storage time of biodiesels using Rancimat methods. The microbial oil and the biodiesel obtained from microbial oil have been characterized with storage stability due to various oxidizing and thermal damage. Here, the microbial fuels were subject to Rancimat analysis and found to have high thermal-oxidative stability of 18 and 8.78 h for biodiesel and oil, respectively. The storage stability resulting from storage conditions was extrapolated for biodiesel and oil and has been found to be 1.62 and 0.54 years, respectively. The infrared spectroscopic analysis reveals the degree of oxidation found after the induction time was reached and shows the characteristic peaks for degradation products. Gas chromatography revealed the compounds that were responsible for the stability as well as the amount of degradation products left.
AbstractList Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there are only few articles dealing with the stability of the microbial biofuels. Hence, this study aimed at characterizing the storage time of biodiesels using Rancimat methods. The microbial oil and the biodiesel obtained from microbial oil have been characterized with storage stability due to various oxidizing and thermal damage. Here, the microbial fuels were subject to Rancimat analysis and found to have high thermal-oxidative stability of 18 and 8.78 h for biodiesel and oil, respectively. The storage stability resulting from storage conditions was extrapolated for biodiesel and oil and has been found to be 1.62 and 0.54 years, respectively. The infrared spectroscopic analysis reveals the degree of oxidation found after the induction time was reached and shows the characteristic peaks for degradation products. Gas chromatography revealed the compounds that were responsible for the stability as well as the amount of degradation products left.
Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there are only few articles dealing with the stability of the microbial biofuels. Hence, this study aimed at characterizing the storage time of biodiesels using Rancimat methods. The microbial oil and the biodiesel obtained from microbial oil have been characterized with storage stability due to various oxidizing and thermal damage. Here, the microbial fuels were subject to Rancimat analysis and found to have high thermal-oxidative stability of 18 and 8.78 h for biodiesel and oil, respectively. The storage stability resulting from storage conditions was extrapolated for biodiesel and oil and has been found to be 1.62 and 0.54 years, respectively. The infrared spectroscopic analysis reveals the degree of oxidation found after the induction time was reached and shows the characteristic peaks for degradation products. Gas chromatography revealed the compounds that were responsible for the stability as well as the amount of degradation products left.Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there are only few articles dealing with the stability of the microbial biofuels. Hence, this study aimed at characterizing the storage time of biodiesels using Rancimat methods. The microbial oil and the biodiesel obtained from microbial oil have been characterized with storage stability due to various oxidizing and thermal damage. Here, the microbial fuels were subject to Rancimat analysis and found to have high thermal-oxidative stability of 18 and 8.78 h for biodiesel and oil, respectively. The storage stability resulting from storage conditions was extrapolated for biodiesel and oil and has been found to be 1.62 and 0.54 years, respectively. The infrared spectroscopic analysis reveals the degree of oxidation found after the induction time was reached and shows the characteristic peaks for degradation products. Gas chromatography revealed the compounds that were responsible for the stability as well as the amount of degradation products left.
Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there are only few articles dealing with the stability of the microbial biofuels. Hence, this study aimed at characterizing the storage time of biodiesels using Rancimat methods. The microbial oil and the biodiesel obtained from microbial oil have been characterized with storage stability due to various oxidizing and thermal damage. Here, the microbial fuels were subject to Rancimat analysis and found to have high thermal-oxidative stability of 18 and 8.78 h for biodiesel and oil, respectively. The storage stability resulting from storage conditions was extrapolated for biodiesel and oil and has been found to be 1.62 and 0.54 years, respectively. The infrared spectroscopic analysis reveals the degree of oxidation found after the induction time was reached and shows the characteristic peaks for degradation products. Gas chromatography revealed the compounds that were responsible for the stability as well as the amount of degradation products left.
Author Tamilalagan, Anbarasan
Singaram, Jayanthi
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  organization: Government College of Technology
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Snippet Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there...
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SubjectTerms Alternative fuels
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Biodegradation
biodiesel
Biodiesel fuels
Biofuels
Chromatography
Degradation
Degradation products
Diesel
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental science
Gas chromatography
gas chromatography-mass spectrometry
Industrial wastes
Infrared analysis
Infrared spectroscopy
Mass spectrometry
Mass spectroscopy
microbial oils
Microorganisms
Oxidation
oxidative stability
Research Article
Shelf life
spectral analysis
Stability analysis
Storage conditions
storage quality
Storage stability
storage time
Waste Water Technology
Water Management
Water Pollution Control
Yeast
yeasts
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Title Oxidation stability of yeast biodiesel using Rancimat analysis: validation using infrared spectroscopy and gas chromatography–mass spectrometry
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Volume 26
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