Monodentate, Didentate, and Tridentate Ligation of a Schiff-Base Ligand in a Tetranuclear Zinc(II) Complex

A tetranuclear zinc(II) complex with 2,6-bis(salicylideneaminomethyl)-4-methylphenol (H3L), [Zn4(L)2(pz)2]•2CH3CN (Hpz = pyrazole), was synthesized and characterized by 1H NMR spectroscopy and a single-crystal X-ray diffraction method. Each Schiff-base L3- acts as a monodentate, a didentate, and a t...

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 74; no. 1; pp. 99 - 100
Main Authors Mikuriya, Masahiro, Ikemi, Shinichiro, Lim, Jong-Wan
Format Journal Article
LanguageEnglish
Published Tokyo The Chemical Society of Japan 01.01.2001
Chemical Society of Japan
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Summary:A tetranuclear zinc(II) complex with 2,6-bis(salicylideneaminomethyl)-4-methylphenol (H3L), [Zn4(L)2(pz)2]•2CH3CN (Hpz = pyrazole), was synthesized and characterized by 1H NMR spectroscopy and a single-crystal X-ray diffraction method. Each Schiff-base L3- acts as a monodentate, a didentate, and a tridentate ligand for four zinc atoms to form a Z-shaped tetranuclear structure.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.74.99