Solid-state Chemical Reaction Synthesis and Characterization of Lanthanum Tartrate Nanocrystallites Under Ultrasonication Spectra

• Published in: IOP conference series. Materials Science and Engineering Vol. 242; no. 1; pp. 12023 - 12028
• Main Authors: Li, Dao-hua, He, Shao-fen, Chen, Jie, Jiang, Cheng-yan, Yang, Cheng
• Format: Journal Article
• Language: English
• Published: Bristol IOP Publishing 01.09.2017
• Subjects: Chemical reactions; Crystallization; Deionization; Electron diffraction; Ethanol; Functional groups; Infrared analysis; Infrared spectra; Lanthanum; Lanthanum chlorides; Matching; Morphology; Nanocrystals; Nanoparticles; Particle size; Particle size distribution; Polyethylene glycol; Raw materials; Reaction synthesis; Room temperature; Solid phases; Solid state; Solvents; Surfactants; Tartaric acid
• ISSN: 1757-8981; 1757-899X
• DOI: 10.1088/1757-899X/242/1/012023

Under near room temperature, by using sodium tartrate, lanthanum trichloride, lanthanum acetate, and lanthanum nitrate as reactants, we synthesize the lanthanum tartrate nanocrystals in one step under the condition that the infrared lamp is irradiated and the polyethylene glycol 400 is used as the surfactant, where the synthesis method of nanoparticles by solid phase chemical reaction is used. Deionized water after washing with ethanol washes. Tartaric acid lanthanum crystalline powder is gotten, respectively. Analyze solid products phase using X-ray diffraction (XRD) and electron diffraction; characterize the functional groups structure with infrared spectra, and analyzethe change of functional groups in drugs before and after reaction; observe the size, shape, and size distribution of particlesby transmission electron microscopy(TEM). Testing 3 types of tartaric acid crystal powder of lanthanum are nano-crystallization, solid products are granular and relatively uniform in size, with an average particle diameter of about 40 nm, and the yield rate is approximately 92.3%. Furthermore, during the synthesis, the solid-state reaction conditions including raw materials, matching proportion of reactants, additions of inert substance, addition of trace solvents, surfactants and porphyrization time, etc, all have some influence on the morphology, particle size and size distribution of the final products. During the synthesis of the lanthanum tartrate nanocrystallites, the solid state reaction conditions such as changing reactant, matching proportion of reactant, adding inert substance, joining a little solvent or surface active solvent and grinding at different times may influence morphology, particle size and the size distribution of final products.