CFD investigating the effects of different operating conditions on the performance and the characteristics of a high-temperature PEMFC

• Published in: Energy (Oxford) Vol. 35; no. 1; pp. 16 - 27
• Main Authors: Su, A., Ferng, Y.M., Shih, J.C.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 2010; Elsevier
• Subjects: Applied sciences; CFD fuel cell model, Performance curve, Operating condition effect; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; High-temperature PEMFC; High-temperature PEMFC; CFD fuel cell model, Performance curve, Operating condition effect; Performance characteristic; Cation exchange membrane; High temperature; Performance; Modeling; Fuel cell; Operating conditions
• ISSN: 0360-5442
• DOI: 10.1016/j.energy.2009.08.033

The effects of different operating conditions on the performance and the characteristics of a high-temperature proton exchange membrane fuel cell (PEMFC) are investigated using a three-dimensional (3-D) computational fluid dynamics (CFD) fuel-cell model. This model consists of the thermal-hydraulic equations and the electrochemical equations. Different operating conditions studied in this paper include the inlet gas temperature, system pressure, and inlet gas flow rate, respectively. Corresponding experiments are also carried out to assess the accuracy of this CFD model. Under the different operating conditions, the PEMFC performance curves predicted by the model correspond well with the experimentally measured ones. The performance of PEMFC is improved as the increase in the inlet temperature, system pressure or flow rate, which is precisely captured by the CFD fuel cell model. In addition, the concentration polarization caused by the insufficient supply of fuel gas can be also simulated as the high-temperature PEMFC is operated at the higher current density. Based on the calculation results, the localized thermal-hydraulic characteristics within a PEMFC can be reasonably captured. These characteristics include the fuel gas distribution, temperature variation, liquid water saturation distribution, and membrane conductivity, etc.