Recovery of magnesium from Uyuni salar brine as high purity magnesium oxalate

• Published in: Hydrometallurgy Vol. 138; pp. 93 - 99
• Main Authors: Tran, Khuyen Thi, Van Luong, Tri, An, Jeon-Woong, Kang, Dong-Jun, Kim, Myong-Jun, Tran, Tam
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.06.2013
• Subjects: Calcium oxalate; Lithium; Magnesium; Magnesium oxalate; Oxalates; Oxalic acid; Precipitates; Precipitation; Recovery; Salt water; Selective recovery of magnesium; Uyuni salar brine; Uyuni salar brine; Selective recovery of magnesium; Calcium oxalate; Oxalic acid; Magnesium oxalate
• ISSN: 0304-386X; 1879-1158
• DOI: 10.1016/j.hydromet.2013.05.013

Containing 10.2 Mt Li, Salar de Uyuni is known to be the richest resource of Li in the world. A high Mg/Li mass ratio of 21.2:1 of the Uyuni salar brine used in this study is a significant factor hindering the effective lithium recovery. Stabcal modelling was first conducted to study the conditions and chemical speciation of various species involved in the selective precipitation of Mg and Ca oxalate. Along with the addition of oxalic acid, the effect of pH was then studied in order to determine optimal conditions to selectively remove Ca and achieve high Mg yield subsequently. At an Oxalate/Ca molar ratio of 6.82:1 and pH <1, ~80% of Ca could be removed from brine without co-precipitation of Mg oxalate. A NaOH/Mg/Oxalate molar ratios of 1.95:1:1 to 3.21:1:1.62 in the range of pH3–5.5 was used for the Mg precipitation. A recovery of >95% Mg was obtained (precipitate containing mostly Mg oxalate) together with the K and Li losses of up to 35% from the original brine. Washing would remove Li, K contaminants and the co-precipitated sodium sulphate and oxalate. Their absence from the final precipitate was confirmed by XRD analysis. The high purity (99.5% grade) Mg precipitate obtained could be used as a precursor for MgO production. •Mg was recovered from Uyuni salar brine which contains high Mg/Li mass ratio of 21.2:1•Ca and Mg could be precipitated from brine separately by using oxalic acid.•About 80% Ca could be removed from brine at pH<1.•About 95% Mg was recovered in the range of pH3–5.5.•Mg oxalate product contained 0.5% impurities (Li, K, Na) and was 99.5% pure.