Comparative study of Ag(I) selective poly(vinyl chloride) membrane sensors based on newly developed Schiff-base lariat ethers derived from 4,13-diaza-18-crown-6

• Published in: Analytica chimica acta Vol. 631; no. 2; pp. 161 - 169
• Main Authors: Gupta, Vinod K., Pal, Manoj K., Singh, Ashok K.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 12.01.2009; Elsevier
• Subjects: Ag(I); Analytical chemistry; Chemistry; Electrochemical methods; Exact sciences and technology; General, instrumentation; Ion-selective electrodes; Schiff-base lariat ether; Sensors; Ag(I); Sensors; Ion-selective electrodes; Schiff-base lariat ether; Performance evaluation; Crown compound; Blood; Schiff base; DBP; Lariat ether; Membrane; Ionophore; Polyvinyl chloride; Methanol; Ethanol; Non ionic surfactant; Sodium compound; Chemical sensor; Lauryl sulfate; Ion selective electrode; Plasticizer; Response time; Acetonitrile; Cations; Potassium; Comparative study; Silver I; Borates
• ISSN: 0003-2670; 1873-4324
• DOI: 10.1016/j.aca.2008.10.033

The six Schiff-base lariat ether chelates based on 4,13-diaza-18-crown ether, have been synthesized and explored as a neutral ionophores for preparing poly(vinyl chloride) based membrane sensors selective to silver(I). The addition of potassium tetrakis(4-chlorophenyl) borate and various plasticizers, viz., o-NPOE, DBP, DBBP, DOP and CN has been found to substantially improve the performance of the sensors. The best performance was obtained with the sensor no. 5 having membrane of chelate (A 6) with composition (w/w) chelate (2.8%):PVC (45.7%): o-NPOE (48.6%):KTpClPB (2.8%). This sensor exhibits Nernstian response with slope 59.3 mV/decade of activity in the concentration range 5.6 × 10 −8–1.0 × 10 −1 M Ag(I), performs satisfactorily over wide pH range of (3.0–8.0) with a fast response time (12 s). The sensor was also found to work satisfactorily in partially non-aqueous media up to 25% (v/v) content of acetonitrile, methanol or ethanol and can tolerate the concentration 1.0 × 10 −2 M of ionic (SDS, TBC) and nonionic (Triton X-100) surfactants. The proposed sensor can be used over a period of 4 months without significant drift in potentials. The response of the sensor was highly selective to Ag + over a large number of cations and it could therefore be used for Ag + estimation in blood of occupationally exposed persons.