A new efficient forest biowaste as biosorbent for removal of cationic heavy metals

• Published in: Bioresource technology Vol. 175; pp. 629 - 632
• Main Authors: Kim, Namgyu, Park, Munsik, Park, Donghee
• Format: Journal Article
• Language: English
• Published: England 01.01.2015
• Subjects: Adsorption; Cadmium - chemistry; Cadmium - isolation & purification; Cationic; Cations; Chestnut; Fagaceae - chemistry; Forestry; Forests; Heavy metals; Hydrogen-Ion Concentration; Isotherms; Kinetics; Lead - chemistry; Lead - isolation & purification; Mathematical analysis; Mathematical models; Pinus - chemistry; Plant Bark - chemistry; Republic of Korea; Spectroscopy, Fourier Transform Infrared; Uptakes; Waste Products; Biosorbent; Biosorption; Forest biowaste; Chestnut bur; Heavy metal
• ISSN: 0960-8524; 1873-2976
• DOI: 10.1016/j.biortech.2014.10.092

Among various forest biowastes, chestnut bur had the highest uptake values of Cd(II) and Pb(II), and these values were higher than those of agricultural biowastes used as comparable biosorbents. This study is the first report showing the high potential of chestnut bur as biosorbent for the removal of cationic heavy metals. Pseudo-second-order equation satisfactorily described the biosorption behaviors of both metals. Biosorption rate of Pb(II) was 3.12 times higher than that of Cd(II). Langmuir model could fit the equilibrium isotherm data better than Freundlich model. The maximum uptake capacities of Cd(II) and Pb(II) were determined to be 34.77mg/g and 74.35mg/g, respectively. FTIR study showed that carboxyl group on the biosorbent was involved in biosorbing the cationic metals. In conclusion, abundant and cheap forest biowastes, especially chestnut bur, is a potent candidate for efficient biosorbent capable of removing toxic heavy metals from aqueous solutions.