A high-temperature and high-pressure cell for in situ visualization of reaction processes by neutron imaging

• Published in: Review of Scientific Instruments Vol. 94; no. 8
• Main Authors: Abe, Jun, Matsumoto, Yoshihiro, Miyazaki, Tsukasa, Noma, Takashi
• Format: Journal Article
• Language: English
• Published: United States AIP Publishing 01.08.2023; American Institute of Physics
• Subjects: Decomposition reactions; High pressure; High temperature; Hydrothermal reactions; Image transmission; Pressure cells; Reforming; Scientific apparatus & instruments
• ISSN: 0034-6748; 1089-7623; 1089-7623
• DOI: 10.1063/5.0159685

This study developed a high-temperature and high-pressure (HTHP) cell for in situ neutron imaging of hydrothermal reactions. The cell’s maximum temperature and pressure were 500 °C and 50 MPa, respectively, and its vessel for observing reactions comprised SUS316 stainless steel. Neutron transmission images were obtained to observe the behavior of sub- and supercritical water and the decomposition of two plastics (polypropylene and polyethylene) at HTHP. The images showed that water’s density and phase changed with temperature and pressure, affecting neutron transmission (and thus image brightness). The plastics began to melt and change shape at 150–200 °C, and they decomposed at 500 °C and 20 MPa. This study provides a basis for future research using the HTHP cell to examine various reactions such as the decomposition of biomass samples, the reforming of heavy oil, and the synthesis of nano-materials using sub- and supercritical water.