Efficient Copper(II)-Catalyzed Transamidation of Non-Activated Primary Carboxamides and Ureas with Amines

Amid(e) them all: Primary carboxamides and ureas react with aromatic and aliphatic amines in the presence of a copper catalyst to give a wide range of functionalized amides (see scheme).

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Bibliographic Details
Published inAngewandte Chemie (International ed.) Vol. 51; no. 16; pp. 3905 - 3909
Main Authors Zhang , Min, Imm, Sebastian, Bähn, Sebastian, Neubert, Lorenz, Neumann, Helfried, Beller, Matthias
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 16.04.2012
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Aliphatic amines
Amides
Amides - chemistry
Amination
Amines
Amines - chemistry
Catalysis
Catalysts
Chemistry
Chemistry, Multidisciplinary
Copper
Copper - chemistry
homogeneous catalysis
Physical Sciences
Science & Technology
Stereoisomerism
transamidation
Urea - chemistry
Ureas
amides
ACTIVATION
AMIDE SYNTHESIS
CONVERSION
BORROWING HYDROGEN
OXIDATIVE AMIDATION
amines
RUTHENIUM-CATALYZED AMINATION
ALCOHOLS
homogeneous catalysis
ARYL HALIDES
copper
DERIVATIVES
transamidation
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Summary:Amid(e) them all: Primary carboxamides and ureas react with aromatic and aliphatic amines in the presence of a copper catalyst to give a wide range of functionalized amides (see scheme).
Bibliography:This work has been supported by Evonik and the Deutsche Forschungsgemeinschaft (Leibniz Prize). Z.M. thanks the Alexander von Humboldt Foundation for a grant.
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ArticleID:ANIE201108599
Alexander von Humboldt Foundation
Deutsche Forschungsgemeinschaft
ark:/67375/WNG-FCWV42H9-C
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201108599