Pyramidal texturing of silicon solar cell with TMAH chemical anisotropic etching

• Published in: Solar energy materials and solar cells Vol. 90; no. 15; pp. 2319 - 2328
• Main Authors: Papet, P., Nichiporuk, O., Kaminski, A., Rozier, Y., Kraiem, J., Lelievre, J.-F., Chaumartin, A., Fave, A., Lemiti, M.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Amsterdam Elsevier B.V 01.09.2006; Elsevier
• Subjects: Applied sciences; Energy; Engineering Sciences; Exact sciences and technology; Light trapping; Micro and nanotechnologies; Microelectronics; Natural energy; Photovoltaic conversion; Reflectance; Solar cells; Solar cells. Photoelectrochemical cells; Solar energy; Texturing; TMAH; Solar cells; Light trapping; Texturing; TMAH; Reflectance; Silicon solar cells; Potassium hydroxide; Silicon coating; Chemical etching; Texture; Single crystal; Ammonium hydroxide; High efficiency; Antireflection coating; Surface conditions
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/j.solmat.2006.03.005

High-efficiency silicon solar cells need a textured front surface to reduce reflectance and to improve light trapping. Texturing of monocrystalline silicon is usually done in alkaline solutions. These solutions are cheaper, but are pollutants of silicon technologies. In this paper, we investigate an alternative solution containing tetramethyl ammonium hydroxide ((CH 3) 4NOH, TMAH ). This study shows the influence of different parameters (concentration, agitation, duration and temperature), to obtain uniform and reliable pyramidal texturization on different silicon surfaces (as cut, etched and polished). Under optimized conditions, TMAH-textured surface led to an average weighted reflectance of 13%, without any antireflection coating independent of the initial silicon surface. Unlike potassium hydroxide (KOH) texturing solution, characterization of silicon oxide layer contamination after TMAH texturing process revealed no pollution, and passivation is less affected by TMAH than by KOH texturization.