The CO2 Absorption in Flue Gas Using Mixed Ionic Liquids

• Published in: Molecules (Basel, Switzerland) Vol. 25; no. 5; p. 1034
• Main Authors: Wu, Guoqing, Liu, Ying, Liu, Guangliang, Pang, Xiaoying
• Format: Journal Article
• Language: English
• Published: MDPI 25.02.2020; MDPI AG
• Subjects: absorption; carbon dioxide; flue gas; ionic liquids
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules25051034

Because of the appealing properties, ionic liquids (ILs) are believed to be promising alternatives for the CO2 absorption in the flue gas. Several ILs, such as [NH2emim][BF4], [C4mim][OAc], and [NH2emim[OAc], have been used to capture CO2 of the simulated flue gas in this work. The structural changes of the ILs before and after absorption were also investigated by quantum chemical methods, FTIR, and NMR technologies. However, the experimental results and theoretical calculation showed that the flue gas component SO2 would significantly weaken the CO2 absorption performance of the ILs. SO2 was more likely to react with the active sites of the ILs than CO2. To improve the absorption capacity, the ionic liquid (IL) mixture [C4mim][OAc]/ [NH2emim][BF4] were employed for the CO2 absorption of the flue gas. It is found that the CO2 absorption capacity would be increased by about 25%, even in the presence of SO2. The calculation results suggested that CO2 could not compete with SO2 for reacting with the IL during the absorption process. Nevertheless, SO2 might be first captured by the [NH2emim][BF4] of the IL mixture, and then the [C4mim][OAc] ionic liquid could absorb more CO2 without the interference of SO2.