Synthesis of mesomeric betaine compounds with imidazolium-enolate structure
The synthesis of a heterocyclic mesomeric betaine by quaternization reaction of 1-butylimidazole and tetrabromo-1,4-benzoquinone is presented. The structure was verified by means of X-ray single-crystal analysis, NMR and IR spectroscopy. Inclusion complexes of the heterocyclic mesomeric betaine with...
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Published in | Beilstein journal of organic chemistry Vol. 8; no. 1; pp. 390 - 397 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Germany
Beilstein-Institut
13.03.2012
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Subjects | |
Online Access | Get full text |
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Summary: | The synthesis of a heterocyclic mesomeric betaine by quaternization reaction of 1-butylimidazole and tetrabromo-1,4-benzoquinone is presented. The structure was verified by means of X-ray single-crystal analysis, NMR and IR spectroscopy. Inclusion complexes of the heterocyclic mesomeric betaine with randomly methylated (1.8) β-cyclodextrin were investigated by UV-vis spectroscopy. Furthermore, the reaction conditions were applied to poly(vinylimidazole) and 1,4-bis(1H-imidazol-1-yl)butane to obtain functionalized polymer networks and condensate polymers, respectively. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1860-5397 1860-5397 |
DOI: | 10.3762/bjoc.8.42 |