Studies on the Metabolism of Unsaturated Fatty Acids. III. Structural Determination of cis- and trans-Isomers of 3- or 2-Alkenoic Acids by Nuclear Magnetic Resonance Spectroscopy using a Chemical Shift Reagent

Nuclear magnetic resonance spectroscopy with a lanthanide chemical shift reagent was applied for the structural determination of cis-and trans-isomers of 3-alkenoic acids, prepared as substrates for some enzyme reactions related to fatty acid metabolism. The configuration of N-acetylcysteamine deriv...

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Published inChemical & pharmaceutical bulletin Vol. 28; no. 8; pp. 2347 - 2350
Main Authors MIZUGAKI, MICHINAO, HOSHINO, TOSHIAKI, ITO, YOKO, SAKAMOTO, TAKAO, SHIRAISHI, TAKAYUKI, YAMANAKA, HIROSHI
Format Journal Article
LanguageEnglish
Published Tokyo The Pharmaceutical Society of Japan 1980
Japan Science and Technology Agency
Subjects
trans-3-alkenoic acids
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Summary:Nuclear magnetic resonance spectroscopy with a lanthanide chemical shift reagent was applied for the structural determination of cis-and trans-isomers of 3-alkenoic acids, prepared as substrates for some enzyme reactions related to fatty acid metabolism. The configuration of N-acetylcysteamine derivatives of cis-2-alkenoic acids was also determined by the same technique.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.28.2347