Magic Numbers in the Solvation of the Propofol Dimer

Five waters make a pentagon: Formation of particularly stable propofol2(H2O)5 clusters in propofol/water/He expansions is observed. Their origin seems to be related to the formation of particularly stable pentameric water clusters.

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Bibliographic Details
Published inChemphyschem Vol. 14; no. 8; pp. 1558 - 1562
Main Authors León, Iker, Millán, Judith, Cocinero, Emilio J., Lesarri, Alberto, Fernández, José A.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 03.06.2013
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
Subjects
Chemistry
Dimerization
Exact sciences and technology
General and physical chemistry
Helium - chemistry
Hydrogen Bonding
hydrogen bonds
IR spectroscopy
Isomerism
laser spectroscopy
Mass Spectrometry
Propofol - chemistry
Solutions
Solvation. Solvent properties
Spectrophotometry, Infrared
supersonic expansions
van der Waals forces
Water - chemistry
Infrared spectrometry
supersonic expansions
Solvation
Laser
Van der Waals interaction
Dimer
laser spectroscopy
van der Waals forces
Expansion
IR spectroscopy
hydrogen bonds
Hydrogen bond
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Summary:Five waters make a pentagon: Formation of particularly stable propofol2(H2O)5 clusters in propofol/water/He expansions is observed. Their origin seems to be related to the formation of particularly stable pentameric water clusters.
Bibliography:UPV/EHU - No. UFI 11/23
ark:/67375/WNG-MMHW17T8-B
ArticleID:CPHC201300205
Spanish ministry of Science and Innovation-MICINN - No. 2010/CSD2007-00013; No. CTQ2011-22923; No. CTQ2009-14364; No. CTQ2012-39132
istex:4B8B44B9082076A15DB8E3600603A96755E6F5EA
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1439-4235
1439-7641
DOI:10.1002/cphc.201300205