Studies on the Reactions of Heterocyclic Compounds. II. Syntheses and Some Reactions of 1, 6-Phenanthroline N-Oxides

• Published in: Chemical & pharmaceutical bulletin Vol. 17; no. 7; pp. 1511 - 1514
• Main Authors: KOBAYASHI, YOSHIRO, KUMADAKI, ITSUMARO, MORINAGA, KUNIO
• Format: Journal Article
• Language: English
• Published: Tokyo The Pharmaceutical Society of Japan 1969; Japan Science and Technology Agency

1, 6-Phenanthroline was synthesized from 4-aminoquinoline by the Skraup reaction using sulfo-mix, and N-oxidation was carried out in various ways to obtain 6-oxide and 1, 6-dioxide. Reactions of 6-oxide with acetic anhydride and with phosphoryl chloride and the Reissert reaction were carreid out and...