Initiation and propagation of pitting and crevice corrosion of hydrogen-containing passive films on X70 micro-alloyed steel

• Published in: Electrochimica acta Vol. 49; no. 5; pp. 703 - 714
• Main Authors: Zeng, Y.M., Luo, J.L., Norton, P.R.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 25.02.2004; Elsevier
• Subjects: Applied sciences; Corrosion; Corrosion mechanisms; Crevice corrosion; Exact sciences and technology; Hydrogen; Metals. Metallurgy; Micro-alloyed steel; Pitting; Pitting; Crevice corrosion; Hydrogen; Micro-alloyed steel; Pitting corrosion; Corrosion mechanism; Pitting: Crevice corrosion; Electrochemical corrosion; Corrosion potential; Localized corrosion; Pitting potential; Low alloy steel
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2003.09.024

Hydrogen promoted initiation and propagation of pitting and crevice corrosion of X70 micro-alloyed steel were characterized by potential dynamic measurements, the scanning reference electrode technique (SRET) and electrochemical impedance spectra (EIS). At open circuit potential, in situ SRET results show that hydrogen accelerates the nucleation and propagation of pitting of X70 steel. The pitting potential E p of X70 steel gradually decreases with an increase of chloride ion concentration in NaHCO 3 solution. Pre-charged hydrogen does not have a significant effect on the pitting potential E p and open circuit potential E corr of the steel in 0.5 M NaHCO 3 solution. However, a synergistic effect of hydrogen and Cl − on the anodic dissolution and pitting potential of X70 steel is observed in 0.5 M NaHCO 3 solution containing chloride ions. When crevices are present in X70 steel, hydrogen accelerates the initiation and progress of crevice corrosion. The mechanisms by which hydrogen promotes the initiation and propagation of pitting and crevice corrosion are proposed and discussed.