Asymmetric reverse osmosis sulfonated poly(arylene ether sulfone) copolymer membranes

• Published in: Journal of membrane science Vol. 452; pp. 193 - 202
• Main Authors: Stevens, Derek M., Mickols, Bill, V. Funk, Caleb
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.02.2014; Elsevier
• Subjects: Applied sciences; Asymmetric membranes; Asymmetry; Chemistry; Colloidal state and disperse state; Copolymers; Exact sciences and technology; Exchange resins and membranes; Forms of application and semi-finished materials; General and physical chemistry; Membranes; Monovalent and divalent rejection; Phase shift; Polyamide resins; Polymer industry, paints, wood; Rejection; Reverse osmosis; Sulfonated poly(arylene ether sulfone); Sulfones; Technology of polymers; Monovalent and divalent rejection; Sulfonated poly(arylene ether sulfone); Reverse osmosis; Asymmetric membranes; Membrane separation; Polymeric membrane; Asymmetric membrane; Copolymer
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2013.10.042

Reverse osmosis membranes based on partially disulfonated copolymers of biphenol and aryl sulfone (BPS) have been studied in an asymmetric architecture. In these films, BPS represents both the porous support and solute rejection layer of the membrane. A procedure was developed to fabricate these asymmetric films through phase inversion of BPS solutions. Recipe optimization and the inclusion of several post-treatment steps to densify the rejection layer and heal defects gave the largest improvements in salt passage and are described in detail. A strong dependence of the final salt passage on ionic strength and temperature of the annealing solution is demonstrated. Under 2000ppm NaCl and 15.5bar test conditions, membranes were developed with salt passage from 0.34% to 1.81% across a flux range of 2.5–20lmh. This performance represents a step change in the capability of BPS membranes for reverse osmosis. To achieve competitiveness with commercial polyamide membranes, several challenges required for continued improvements and commercialization are discussed. [Display omitted] •Asymmetric reverse osmosis membranes were with a disulfonated copolymer of biphenol and aryl sulfone.•Casting conditions were tuned to provide the optimum balance between water permeability and salt rejection.•Membranes were post-treated by annealing and coating to further improve rejection.•Salt rejection in feeds contained mixed valency was examined.