Enhanced rectification through polymer-gold nanoparticle interaction

• Published in: Synthetic metals Vol. 155; no. 1; pp. 39 - 44
• Main Authors: Dewald, James L., Wondmagegn, Wudyalew T., Ellis, Amanda V., Curran, Seamus A.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 15.10.2005; Amsterdam Elsevier Science; New York, NY
• Subjects: Applied sciences; Composites; Exact sciences and technology; Forms of application and semi-finished materials; Gold nanoparticles; Near-field scanning optical microscopy (NSOM); Poly( m-phenylenevinylene- co-2,5-dioctoxy- p-phenlenevinylene) (PmPV); Polymer industry, paints, wood; Raman scattering; Schottky diodes; Technology of polymers; Schottky diodes; Near-field scanning optical microscopy (NSOM); Poly( m-phenylenevinylene- co-2,5-dioctoxy- p-phenlenevinylene) (PmPV); Raman scattering; Gold nanoparticles; Rectifier effect; Gold; Mixing; Voltage current curve; Poly(m-phenylenevinylene-co-2,5-dioctoxy-p-phenlenevinylene) (PmPV); Phenylenevinylene derivative copolymer; Surface topography; Experimental study; Metal particle; Conjugated copolymer; Optical properties; Alternating copolymer; Nanocomposite; Manufacturing; Schottky barrier diode; Phenylenevinylene copolymer; Optical absorption; Growth from solution
• ISSN: 0379-6779; 1879-3290
• DOI: 10.1016/j.synthmet.2005.05.021

In this paper we report the fabrication of a new nanocomposite based on poly( m-phenylenevinylene- co-2,5-dioctoxy- p-phenlenevinylene) (PmPV) and gold (PmPV-gold) nanoparticles. Characterization of this new material using UV–visible absorption spectroscopy, Raman spectroscopy and near-field scanning optical microscopy showed encapsulation of the gold nanoparticles (∼20 nm) by the polymer. Wrapping of gold nanoparticles by the polymer provided higher quality electrical characteristics than the polymer alone, indicated by superior rectification and Schottky diode characteristics with ideality factors of 27.69 and 1.32 for pure PmPV and PmPV-gold nanocomposite cells, respectively. Barrier heights, calculated from the reverse saturation current, were 0.865 and 0.559 eV for PmPV and PmPV-gold nanocomposite cells, respectively.