A review on energy chemistry of fast-charging anodes

With the impetus to accelerate worldwide market adoption of electrical vehicles and afford consumer electronics with better user experience, advancing fast-charging technology is an inevitable trend. However, current high-energy lithium-ion batteries are unable to support ultrafast power input witho...

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Published inChemical Society reviews Vol. 49; no. 12; pp. 386 - 3833
Main Authors Cai, Wenlong, Yao, Yu-Xing, Zhu, Gao-Long, Yan, Chong, Jiang, Li-Li, He, Chuanxin, Huang, Jia-Qi, Zhang, Qiang
Format Journal Article
LanguageEnglish
Published London Royal Society of Chemistry 22.06.2020
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Summary:With the impetus to accelerate worldwide market adoption of electrical vehicles and afford consumer electronics with better user experience, advancing fast-charging technology is an inevitable trend. However, current high-energy lithium-ion batteries are unable to support ultrafast power input without any adverse consequences, with the capacity fade and safety concerns of the mainstream graphite-based anodes being the key technological barrier. The aim of this review is to summarise the fundamentals, challenges, and solutions to enable graphite anodes that are capable of high-rate charging. First, we explore the complicated yet intriguing graphite-electrolyte interface during intercalation based on existing theories. Second, we analyse the key dilemmas facing fast-charging graphite anodes. Finally, some promising strategies proposed during the past few years are highlighted so as to outline current trends and future perspectives in this field. Fundamentals, challenges, and solutions towards fast-charging graphite anodes are summarized in this review, with insights into the future research and development to enable batteries suitable for fast-charging application.
Bibliography:Wenlong Cai received his BS degree from Sichuan University in 2013 and PhD degree from University of Science and Technology of China in 2019. He joined Prof. Qiang Zhang's group as a postdoctoral researcher at the Department of Chemical Engineering in Tsinghua University. His current research interests focus on functional coating of the graphite anode and the transport mechanism of Li ions in the solid electrolyte interphase.
Gao-Long Zhu obtained his PhD from School of Physics in University of Electronic Science and Technology of China in 2018. He is now a postdoc in Department of Chemical Engineering, Tsinghua University. His main areas of research address energy storage materials, including fast charging electrodes, solid electrolytes and separators.
Chong Yan received his bachelor's and master's degrees from Henan Normal University in 2013 and is currently a PhD candidate at Beijing Institute of Technology in Prof. Jia-Qi Huang's group. His research focuses on the interface and ion channel of lithium battery anodes.
Jia-Qi Huang received his BEng (2007) and PhD (2012) degrees in Chemical Engineering from Tsinghua University, China. He is currently a professor in Advanced Research Institute of Multidisciplinary Science (ARIMS) in Beijing Institute of Technology. His research interests focus on the interface phenomenon and design strategies for high-energy-density rechargeable batteries, including Li-S batteries, Li metal batteries, etc.
Qiang Zhang received his bachelor's and PhD degrees from Tsinghua University in 2004 and 2009, respectively. After spending some time at Case Western Reserve University, USA, and Fritz Haber Institute of the Max Planck Society, Germany, he was appointed as a faculty member at Tsinghua University in 2011. His interests are focused on energy materials, including Li-S batteries, Li metal anode, 3D graphene, and electrocatalysts. He was awarded The National Science Fund for Distinguished Young Scholars, Young Top-Notch Talent from China, and Newton Advanced Fellowship from the Royal Society, UK. Currently, he is an associate editor of the Journal of Energy Chemistry and Energy Storage Materials.
Yu-Xing Yao completed his BE from the Department of Chemical Engineering, Tsinghua University in 2019 and is currently a PhD candidate at Tsinghua University. His current research includes battery materials for fast-charging and interfacial chemistry in batteries.
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ISSN:0306-0012
1460-4744
1460-4744
DOI:10.1039/c9cs00728h