The Curious Case of Ketene in Zeolite Chemistry and Catalysis

Ketenes in the limelight: The influential role of ketenes has never been adequately acknowledged in zeolite chemistry and catalysis; unlike other first generation highly reactive intermediates, such as carbocations, carbanions, radicals, and carbenes. In fact, the role that ketenes play during catal...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 57; no. 46; pp. 14982 - 14985
Main Authors Chowdhury, Abhishek Dutta, Gascon, Jorge
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 12.11.2018
EditionInternational ed. in English
Subjects
Carbenes
Catalysis
heterogeneous catalysis
Intermediates
Ketenes
Organic chemistry
reaction mechanisms
spectroscopy
Zeolites
reaction mechanisms
zeolites
heterogeneous catalysis
spectroscopy
ketenes
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Summary:Ketenes in the limelight: The influential role of ketenes has never been adequately acknowledged in zeolite chemistry and catalysis; unlike other first generation highly reactive intermediates, such as carbocations, carbanions, radicals, and carbenes. In fact, the role that ketenes play during catalysis—whether beneficial or detrimental—is a contentious subject that requires further consideration.
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201808480