Total synthesis of 1-oxomiltirone via Suzuki coupling

Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1 and miltirone 4, a versatile intermediate 6 was found. The compound 6 could be used as a precursor A-B-C rings with different oxidative degrees...

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Published inNatural products and bioprospecting Vol. 3; no. 3; pp. 117 - 120
Main Authors Li, Chun-Miao, Geng, Hui-Chun, Li, Ming-Ming, Xu, Gang, Ling, Tie-Jun, Qin, Hong-Bo
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg Springer-Verlag 01.06.2013
Springer Berlin Heidelberg
Springer Nature B.V
Subjects
Biomedical and Life Sciences
Bioorganic Chemistry
diterpenoids
drugs
Food Science
Life Sciences
Medicinal Chemistry
Pharmacology/Toxicology
Plant Biochemistry
Plant Sciences
Short Communication
synthesis
Suzuki coupling
1-oxomiltirone
abietane diterpenes
total synthesis
versatile intermediate
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Abstract Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1 and miltirone 4, a versatile intermediate 6 was found. The compound 6 could be used as a precursor A-B-C rings with different oxidative degrees in selected abietane diterpenes when synthesized through high yield Suzuki reaction and subsequent cyclization, and total synthesis of 1-oxomiltirone (1) has been achieved.
AbstractList Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1 and miltirone 4, a versatile intermediate 6 was found. The compound 6 could be used as a precursor A-B-C rings with different oxidative degrees in selected abietane diterpenes when synthesized through high yield Suzuki reaction and subsequent cyclization, and total synthesis of 1-oxomiltirone (1) has been achieved.
Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1 and miltirone 4 , a versatile intermediate 6 was found. The compound 6 could be used as a precursor A-B-C rings with different oxidative degrees in selected abietane diterpenes when synthesized through high yield Suzuki reaction and subsequent cyclization, and total synthesis of 1-oxomiltirone ( 1 ) has been achieved.
Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1 and miltirone 4, a versatile intermediate 6 was found. The compound 6 could be used as a precursor A-B-C rings with different oxidative degrees in selected abietane diterpenes when synthesized through high yield Suzuki reaction and subsequent cyclization, and total synthesis of 1-oxomiltirone (1) has been achieved. [Figure not available: see fulltext.]
Author Qin, Hong-Bo
Li, Ming-Ming
Geng, Hui-Chun
Ling, Tie-Jun
Xu, Gang
Li, Chun-Miao
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Cites_doi 10.1016/j.tet.2004.12.033
10.1007/s10600-006-0247-7
10.1016/j.tetlet.2008.03.151
10.1016/S0040-4039(00)99274-8
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10.1271/bbb1961.50.2405
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Issue 3
Keywords Suzuki coupling
1-oxomiltirone
abietane diterpenes
total synthesis
versatile intermediate
Language English
License This article is published under license to BioMed Central Ltd. Open Access This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution and reproduction in any medium, provided the original author(s) and source are credited.
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Snippet Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1...
Abietane diterpenes and miltirone series have shown important activities and for medical purposes in order to achieve the total synthesis of 1-oxomiltrone 1...
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SubjectTerms Biomedical and Life Sciences
Bioorganic Chemistry
diterpenoids
drugs
Food Science
Life Sciences
Medicinal Chemistry
Pharmacology/Toxicology
Plant Biochemistry
Plant Sciences
Short Communication
synthesis
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Title Total synthesis of 1-oxomiltirone via Suzuki coupling
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