Enhanced reduction of nitrobenzene derivatives using reusable Ni nanoparticles supported on multi-layered poly(1,2-phenylenediamine)-coated layered double hydroxides

• Published in: Canadian journal of chemistry Vol. 100; no. 6; pp. 412 - 421
• Main Authors: Babamoradi, Jamshid, Ghorbani-Vaghei, Ramin, Alavinia, Sedigheh
• Format: Journal Article
• Language: English
• Published: 1840 Woodward Drive, Suite 1, Ottawa, ON K2C 0P7 Canadian Science Publishing 01.06.2022; NRC Research Press; Canadian Science Publishing NRC Research Press
• Subjects: Aluminum; Analysis; Aniline; catalyse hétérogène; Chemical synthesis; Chemistry; Chemistry, Multidisciplinary; Copolymers; Copper; Cu–Zn–Al LDH; heterogeneous catalysis; Hydroxides; hydroxydes doubles lamellaires à base de Cu–Zn–Al; Identification and classification; Multilayers; Nanocomposites; Nanomaterials; Nanoparticles; nanoparticules de nickel; Nanotechnology; Ni NPs; Nickel; nitroarene reduction; Nitrobenzene; Nitrobenzenes; Oxidation-reduction reaction; Phenylenediamine; Physical Sciences; Reduction; réduction du nitroarene; Science & Technology; Zinc; Iran; NITROARENES; EFFICIENT CATALYST; HYDROGENATION; heterogeneous catalysis; DRUG-DELIVERY; NANOCATALYSTS; POLYMER; nitroarene reduction; Cu-Zn-Al LDH; AROMATIC NITRO; Ni NPs
• ISSN: 0008-4042; 1480-3291
• DOI: 10.1139/cjc-2021-0250

Recently, nanomaterials with layered double hydroxide (LDH) cores have been the subject of intense research regarding their promising applications in organic synthesis. In this study, nitrobenzene reduction is investigated by designing and synthesizing a novel LDH-based heterogeneous catalyst containing a nickel-1,2-phenylenediamine complex. The Cu–Zn–Al LDH was functionalized with copolymer bearing a glycidyl methacrylate (GMA) linkage that makes it suitable for grafting with 1,2-phenylenediamine. Overall, the synthesized LDH@MPS-GMA-PDA-Ni was found to be a highly efficient heterogeneous nanocatalyst that can catalyze nitroarene reduction with high yields under mild conditions.