Size-resolved Pb distribution in the Athabasca River shows snowmelt in the bituminous sands region an insignificant source of dissolved Pb

• Published in: Scientific reports Vol. 7; no. 1; p. 43622
• Main Authors: Javed, Muhammad Babar, Cuss, Chad W., Grant-Weaver, Iain, Shotyk, William
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 06.03.2017; Nature Publishing Group
• Subjects: 704/106/35/824; 704/172/169/209; Bioavailability; Children; Contamination; Creeks & streams; Gasoline; Humanities and Social Sciences; Lead; multidisciplinary; Rivers; Science; Soil sciences; Thorium; Weathering
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/srep43622

Lead (Pb) is a metal of special importance because of its long history of commercial and industrial use, global atmospheric contamination accelerated by the use of gasoline additives, and health effects, with children being especially vulnerable. Global atmospheric Pb pollution reached its zenith in the 1970’s, but subsequent impacts on freshwater aquatic systems are poorly understood. Employing metal-free sampling and handling protocols, we show that snowmelt from the Athabasca bituminous sands region is an insignificant source of dissolved Pb to the Athabasca River (AR). Total Pb in the AR is low, and almost entirely in particulate form. Lead in the suspended solids in the AR exactly follows thorium (Th), a conservative lithophile element, and a linear regression of Pb against Th (Pb = 1.6 × Th + 0.0; R 2  = 0.99) yields a slope identical to the Pb/Th ratio in the Upper Continental Crust. In the “dissolved” fraction, the Pb/Th ratio is equivalent to that of deep, open ocean seawater; and dominated by colloidal forms. Taken together, these results show that the efforts of recent decades to reduce anthropogenic Pb to the environment have been successful: Pb loading to the river can now be explained predominantly by natural processes, namely erosion plus chemical weathering.