Variations in submicron aerosol liquid water content and the contribution of chemical components during heavy aerosol pollution episodes in winter in Beijing

• Published in: The Science of the total environment Vol. 693; p. 133521
• Main Authors: Shen, X.J., Sun, J.Y., Zhang, X.Y., Zhang, Y.M., Zhong, J.T., Wang, X., Wang, Y.Q., Xia, C.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 25.11.2019
• Subjects: Aerosol liquid water content; Heavy aerosol pollution episode; North China Plain; Particle hygroscopicity; Particle hygroscopicity; Aerosol liquid water content; Heavy aerosol pollution episode; North China Plain
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2019.07.327

The aerosol liquid water content (ALWC) of submicron particles (PM1) was calculated in this work by three methods based on the aerosol physical and chemical properties measurement campaigns in winter in Beijing, including (a) the PM1 volume difference between the ambient and dry states by applying the particle number size distribution and particle hygroscopicity measurement; (b) the thermodynamic equilibrium model (ISORROPIA II) based on the chemical composition; and (c) the κ-Köhler theory of chemical composition with a volume mixing scheme. The three methods agreed well with reasonable uncertainties. The ALWC showed an exponential trend depending on the relative humidity (RH), and an abundant ALWC was also favored by the high PM1 mass loading. The contribution of different chemical component to the ALWC was evaluated by the κ-Köhler method, which revealed that during the measurement, the inorganics and organics could contribute to ~80% and ~20%, respectively, under ambient RH conditions, with the largest contributor of ammonium nitrate. When the RH was above 85%, the mass concentration of ALWC was comparable to, or even larger than, that of the dry PM1. [Display omitted] •Aerosol liquid water content (ALWC) mass concentration was estimated based on model and measurement data.•The contribution to ALWC by each chemical component was evaluated.•The contribution of ALWC can be larger than the dry PM1 to the particle mass concentration under high RH condition.•The abundant ALWC promoted the secondary inorganic aerosol formation.