Geochemistry of regional background aerosols in the Western Mediterranean

• Published in: Atmospheric research Vol. 94; no. 3; pp. 422 - 435
• Main Authors: Pey, J., Pérez, N., Castillo, S., Viana, M., Moreno, T., Pandolfi, M., López-Sebastián, J.M., Alastuey, A., Querol, X.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.11.2009; Elsevier
• Subjects: Aerosols; Atmospherics; Clay minerals; Earth, ocean, space; Exact sciences and technology; External geophysics; Meteorology; Mineral dust; PM 10; PM 2.5; Regional; Rural; Speciation; Sulfates; Summer; Winter; Iberian Peninsula; Barcelona Spain; Europe; Africa; Catalonia Spain; Southern Europe; North Africa; Central Africa; Mediterranean Sea; West Mediterranean; Mediterranean Basin; Spain; MED, Spain, Cataluna, Barcelona; MED, Western Mediterranean; Rural; Mineral dust; PM 2.5; Aerosols; PM 10; Regional; Speciation; time variations; aerosols; Insolation; Regional scope; Summer; Recirculation; Spray; Advanced infrared sounder; Precursor; Breeze; ozone; speciation; Mixed layer; Biogenic factor; Winter; Fine particle; Spring(season); Ammonium nitrate; chemical composition; PM
• ISSN: 0169-8095; 1873-2895
• DOI: 10.1016/j.atmosres.2009.07.001

The chemical composition of regional background aerosols, and the time variability and sources in the Western Mediterranean are interpreted in this study. To this end 2002–2007 PM speciation data from an European Supersite for Atmospheric Aerosol Research (Montseny, MSY, located 40 km NNE of Barcelona in NE Spain) were evaluated, with these data being considered representative of regional background aerosols in the Western Mediterranean Basin. The mean PM 10, PM 2.5 and PM 1 levels at MSY during 2002–2007 were 16, 14 and 11 µg/m 3, respectively. After compiling data on regional background PM speciation from Europe to compare our data, it is evidenced that the Western Mediterranean aerosol is characterised by higher concentrations of crustal material but lower levels of OM + EC and ammonium nitrate than at central European sites. Relatively high PM 2.5 concentrations due to the transport of anthropogenic aerosols (mostly carbonaceous and sulphate) from populated coastal areas were recorded, especially during winter anticyclonic episodes and summer midday PM highs (the latter associated with the transport of the breeze and the expansion of the mixing layer). Source apportionment analyses indicated that the major contributors to PM 2.5 and PM 10 were secondary sulphate, secondary nitrate and crustal material, whereas the higher load of the anthropogenic component in PM 2.5 reflects the influence of regional (traffic and industrial) emissions. Levels of mineral, sulphate, sea spray and carbonaceous aerosols were higher in summer, whereas nitrate levels and Cl/Na were higher in winter. A considerably high OC/EC ratio (14 in summer, 10 in winter) was detected, which could be due to a combination of high biogenic emissions of secondary organic aerosol, SOA precursors, ozone levels and insolation, and intensive recirculation of aged air masses. Compared with more locally derived crustal geological dusts, African dust intrusions introduce relatively quartz-poor but clay mineral-rich silicate PM, with more kaolinitic clays from central North Africa in summer, and more smectitic clays from NW Africa in spring.