Calcium oxide a sustainable photocatalyst derived from eggshell for efficient photo-degradation of organic pollutants

• Published in: Journal of Cleaner Production Vol. 270; p. 122294
• Main Authors: Vanthana Sree, G., Nagaraaj, P., Kalanidhi, K., Aswathy, C.A., Rajasekaran, P.
• Format: Journal Article
• Language: English; Japanese
• Published: Elsevier Ltd 10.10.2020; Elsevier BV
• Subjects: Calcination; Calcium oxide; chemical oxygen demand; egg shell; Eggshell; energy-dispersive X-ray analysis; methylene blue; nanocatalysts; nanoparticles; photocatalysis; photocatalysts; Photodegradation; photolysis; pollutants; scanning electron microscopy; Sustainable; toluidine blue; wastes; X-ray diffraction; X-ray photoelectron spectroscopy; Eggshell; Photodegradation; Calcination; Calcium oxide; Sustainable
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2020.122294

Combined application of nanotechnology and waste reutilisation process resulting in effective and cheap nano-photocatalyst have better dye degradation. Calcium oxide nanoparticles (CaO NPs) were synthesized from waste Eggshells (ES) by calcination process and characterized utilizing the analytical techniques such as XRD, SEM, EDAX, XPS and BET analysis. The synthesized CaO NPs were examined for photocatalytic dye degradation of two model dyes such as Methylene blue (MB) and Toluidine blue (TB) in aqueous medium. From the outcomes, it is clear that CaO effectively degraded both the dyes within 15 min (MB in 15 min and TB in 10 min). The studies include optimisation of parameter which found to be 7 pH, 20 ppm dye concentration and 50 mg of catalyst loading were effective operation condition. The kinetics of dye degradation follows pseudo first order, catalyst recycled for 7 cycles and chemical oxygen demand (COD) removal efficiency also analysed for degraded samples. [Display omitted] •Calcium oxide (CaO) an insulating material was derived from waste material (egg shell) in a cheap, eco-friendly, solvent free and single step method.•All Photodegradation reactions were carried in simply water medium, under the solar condition which will be simple and does not required any specific instrument and subject expert in large scale application.•ECaO showed the complete degradation of Toluidine blue dye within 10 min and Methylene blue in 15 min that is shorter than other nanometal oxides.