Ferrite grain refinement in low carbon Cu–P–Cr–Ni–Mo weathering steel at various temperatures in the (α+γ) region

• Published in: Materials characterization Vol. 113; pp. 10 - 16
• Main Authors: Zhang, Chunling, Zhang, Mengmeng, Guo, Tengteng, Yang, Jinfeng, Kong, Yuting, Cai, Dayong, Li, Qiang
• Format: Journal Article
• Language: English
• Published: United States Elsevier Inc 01.03.2016
• Subjects: Atmospheric corrosion; Boundaries; CARBON; Continuous dynamic recrystallization; Corrosion resistant steels; DEFORMATION; Deformation-induced ferrite transformation; DESIGN; DIAGRAMS; DIFFRACTION; Electron backscatter diffraction; ELECTRON TEMPERATURE; Ferrite; FERRITES; GRAIN REFINEMENT; GRAIN SIZE; Grains; MATERIALS SCIENCE; NANOSCIENCE AND NANOTECHNOLOGY; RECRYSTALLIZATION; STEELS; STRAIN RATE; TEMPERATURE RANGE 1000-4000 K; TRANSMISSION ELECTRON MICROSCOPY; Warm compression; WEATHERING; Weathering steels; Warm compression; Continuous dynamic recrystallization; Transmission electron microscopy; Electron backscatter diffraction; Grain refinement; Deformation-induced ferrite transformation
• ISSN: 1044-5803; 1873-4189
• DOI: 10.1016/j.matchar.2015.12.033

Self-designed Cu–P–Cr–Ni–Mo weathering steel was subjected to compression test to determine the mechanism of ferrite grain refinement from 750°C to 925°C. Optical microscopic images showed that ferrite grain size declined, whereas the ferrite volume fraction increased with increasing compression temperature. Electron backscatter diffraction patterns revealed that several low-angle boundaries shifted to high-angle boundaries, thereby generating fine ferrite grains surrounded by high-angle boundaries. Numerous low-angle boundaries were observed within ferrite grains at 750°C, which indicated the existence of pre-eutectoid ferrite. Results showed that ferrite grain refinement could be due to continuous dynamic recrystallization at 750°C and 775°C, and deformation-induced ferrite transformation could be the main mechanism at 800°C and 850°C. Fine equiaxed ferrite grains with size ranging from 1.77μm to 2.69μm were produced in the (α+γ) dual-phase region. There is a close relationship between the microstructure evolution and flow curves during deformation. Fine equiaxed ferrite grains with size ranging from 1.77μm to 2.69μm were achieved in the (α+γ) dual-phase region. Ferrite grain refinement could be due to continuous dynamic recrystallization at 750°C and 775°C, and deformation-induced ferrite transformation at 800°C and 850°C. The occurrence of deformation-induced ferrite transformation and continuous dynamic recrystallization can be monitored by analysis of flow curves and microstructures. Deformation-induced ferrite transformation leads to the dynamic softening in flow curve when temperature just below Ar3, while the dynamic softening in flow curve is ferrite continuous dynamic recrystallization (Special Fig. 5b). [Display omitted] •Compression deformation was operated at temperatures from 750°C to 925°C at a strain rate of 0.1 s–1, and a strain of 1.2.•Fine equiaxed ferrite grains of ~1.77–2.19μm were obtained at 750°C and 775°C via continuous dynamic recrystallization.•Ferrite grain size of ~2.31–2.69μm at 800°C and 850°C can be obtained by deformation-induced ferrite transformation.•With decreasing deformation temperature the average grain size of ferrite decreased while volume fraction increased.•Ferrite refinement was from deformation-induced ferrite to continuous dynamic recrystallization as temperature reduced.