Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Porphyrin-based frameworks, as specific kinds of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), have been widely used in energy-related conversion processes, including the oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and CO 2 reduction reaction (CO 2 RR),...
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| Published in | Chemical Society reviews Vol. 5; no. 4; pp. 254 - 2581 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
01.03.2021
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Porphyrin-based frameworks, as specific kinds of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), have been widely used in energy-related conversion processes, including the oxygen reduction reaction (ORR), oxygen evolution reaction (OER) and CO
2
reduction reaction (CO
2
RR), and also in energy-related storage technologies such as rechargeable Zn-air batteries. This review starts by summarizing typical crystal structures, molecular building blocks, and common synthetic procedures of various porphyrin-based frameworks used in energy-related technologies. Then, a brief introduction is provided and representative applications of porphyrin-based frameworks in ORR, OER, Zn-air batteries, and CO
2
RR are discussed. The performance comparison of these porphyrin-based frameworks in each field is also summarized and discussed, which pinpoints a clear structure-activity relationship. In addition to utilizing highly active porphyrin units for catalytic conversions, regulating the porous structures of porphyrin-based frameworks will enhance mass transfer and growing porphyrin-based frameworks on conductive supports will accelerate electron transfer, which will result in the improvement of the electrocatalytic performance. This review is therefore valuable for the rational design of more efficient porphyrin-based framework catalytic systems in energy-related conversion and storage technologies.
The recent progress made on porphyrin-based frameworks and their applications in energy-related conversion technologies (
e.g.
, ORR, OER and CO
2
RR) and storage technologies (
e.g.
, Zn-air batteries). |
|---|---|
| Bibliography: | Dr Haoquan Zheng is currently an associate professor in the School of Chemistry and Chemical Engineering at Shaanxi Normal University. He received his BS (2006) and PhD (2011) in applied chemistry from Shanghai Jiao Tong University under the supervision of Professor Shunai Che. He worked as a postdoctoral fellow in the group of Professor Xiaodong Zou at Stockholm University. He moved to his current position in July 2016. His research interest lies in the development of hierarchical porous materials with novel structures and functions for drug delivery and heterogeneous catalysis. Dr Hong-Yan Wang received her PhD in organic chemistry in Chinese Academy of Sciences in 2011. In 2014, she joined the School of Chemistry and Chemical Engineering at Shaanxi Normal University as an associate professor. Her research interest concerns artificial photosynthesis using supramolecular systems, coordination compounds, and semiconductors. Now, she is working on the design of a photochemical device for water splitting, CO 2 reduction with Professor Rong Xu, he joined the School of Chemistry and Chemical Engineering at Shaanxi Normal University in 2014. His current research focuses on catalytic reactions of water splitting. reduction and organic synthesis. Prof. Wei Zhang received his BS (2007) in chemistry from Peking University in Beijing, China and PhD degree (2012) from Nanyang Technological University in Singapore with Professor Rong Xu. After postdoctoral work in photocatalytic CO Prof. Rui Cao received his BS (2003) in chemistry from Peking University in Beijing, China and his PhD (2008) from Emory University in Atlanta, Georgia, USA, with Professor Craig L. Hill. He worked as a Postdoctoral Fellow (2008-2009) at Emory University and was the Dreyfus Postdoctoral Fellow (2009-2011) at Massachusetts Institute of Technology with Professor Stephen J. Lippard. In 2011, he became a professor at Renmin University of China, and transferred to Shaanxi Normal University in 2014. His main research interests lie in bioinorganic chemistry and catalysis for energy-related small molecule activation reactions. He served on the Advisory Board of Chemical Society Reviews since 2019. Dr Zuozhong Liang is currently an associate research fellow in the School of Chemistry and Chemical Engineering at Shaanxi Normal University. He received his BS (2011) from Qufu Normal University and PhD (2016) from Beijing University of Chemical Technology under the supervision of Professor Jian-Feng Chen. In July 2016, he joined the research group of Professor Rui Cao. His research interests focus on the design and development of novel functional nanomaterials for application in renewable-energy-related fields. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 ObjectType-Review-3 content type line 23 |
| ISSN: | 0306-0012 1460-4744 1460-4744 |
| DOI: | 10.1039/d0cs01482f |