Two New Triterpene and a New Nortriterpene Glycosides from Phlomis viscosa
The isolation and structure elucidation of two new oleanane‐type triterpene glycosides, 29‐(β‐D‐glucopyranosyloxy)‐2α,3β,23‐trihydroxyolean‐12‐en‐28‐oic acid (=(2α,3β,4α,29α)‐29‐(β‐D‐glucopyranosyloxy)‐2,3,23‐trihydroxyolean‐12‐en‐28‐oic acid; 1) and its C(20)‐epimer, 30‐(β‐D‐glucopyranosyloxy)‐2α,3...
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Published in | Helvetica chimica acta Vol. 87; no. 3; pp. 611 - 619 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Zürich
WILEY-VCH Verlag
01.03.2004
WILEY‐VCH Verlag Wiley |
Subjects | |
Online Access | Get full text |
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Summary: | The isolation and structure elucidation of two new oleanane‐type triterpene glycosides, 29‐(β‐D‐glucopyranosyloxy)‐2α,3β,23‐trihydroxyolean‐12‐en‐28‐oic acid (=(2α,3β,4α,29α)‐29‐(β‐D‐glucopyranosyloxy)‐2,3,23‐trihydroxyolean‐12‐en‐28‐oic acid; 1) and its C(20)‐epimer, 30‐(β‐D‐glucopyranosyloxy)‐2α,3β,23‐trihydroxyolean‐12‐en‐28‐oic acid (=(2α,3β,4α,29β)‐29‐β‐D‐glucopyranosyloxy)‐2,3,23‐trihydroxyolean‐12‐en‐28‐oic acid; 2), and a novel nortriterpene glycoside, (17S)‐2α,18β,23‐trihydroxy‐3,19‐dioxo‐19(18→17)‐ abeo‐28‐norolean‐12‐en‐25‐oic acid β‐D‐glucopyranosyl ester (=(1R,2S,4aS,4bR,6aR,7R,9R,10aS,10bS)‐3,4,4a,4b,5,6,6a,7,8,9,10,10a,10b,11‐tetradecahydro‐1‐hydroxy‐7‐(hydroxymethyl)‐3′,4′,4a,4b,7‐pentamethyl‐2′,8‐ dioxospiro[chrysene‐2(1H),1′‐cyclopentane]‐10a‐carboxylic acid β‐D‐glucopyranosyl ester; 3) from Phlomis viscosa (Lamiaceae) are reported. The structures of the compounds were asigned by means of spectroscopic (IR, 1D‐ and 2D‐NMR, and LC‐ESI‐MS) and chemical (acetylation) methods. |
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Bibliography: | istex:6717935C91D87B3DC6D3F8FF8F17B7B27DE2CB9A ArticleID:HLCA200490059 ark:/67375/WNG-D9F8H3G0-0 |
ISSN: | 0018-019X 1522-2675 |
DOI: | 10.1002/hlca.200490059 |