Dispersion of lanthanoid-coated barium titanate in a paraffin-based extrusion binder system

• Published in: Ceramics international Vol. 32; no. 2; pp. 147 - 156
• Main Authors: Wegmann, Markus, Clemens, Frank, Hendry, Alan, Graule, Thomas
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 2006; Elsevier Science
• Subjects: A. Extrusion; A. Mixing; Applied sciences; B. Fibres; Building materials. Ceramics. Glasses; Ceramic industries; Chemical industry and chemicals; D. BaTiO 3 and titanates; E. PTC devices; Electrotechnical and electronic ceramics; Exact sciences and technology; Technical ceramics; E. PTC devices; A. Mixing; A. Extrusion; D. BaTiO 3 and titanates; B. Fibres; Mixing; Dispersant; Barium titanates; Cerium oxide; Experimental study; Binders; Paraffin; Precursor; Oxide ceramics; Coated material; Powder; Lanthanum oxide; Additive; Extrusion; Manufacturing; Electroceramics
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2005.01.011

For the fabrication of small BaTiO 3-based PTCR elements by ceramic powder extrusion, a submicron barium titanate (BaTiO 3) powder was coated with either CeO 2 or La 2O 3 and mixed with a paraffin-based thermoplastic binder. XPS analysis revealed that the powder surfaces are significantly hydrated and that processing aids are likely to interact with the physisorbed and chemisorbed water rather than directly with the ceramic powder surfaces. From a series of potential C-18 surfactants for this paraffin-based extrusion system, stearic acid was shown to be the most effective dispersant and was consequently used to prepare extrusion feedstocks. Under equivalent extrusion conditions, 50 vol.% CeO 2-coated BaTiO 3 feedstocks always exhibited poorer extrudability than their La 2O 3-coated BaTiO 3 counterparts. Furthermore, the La-doped material invariably sintered to a higher final density than the Ce-doped material. These processability differences can largely be explained by a lower affinity of the stearic acid surfactant for the CeO 2-coated titanate powder.